PROPERTIES OF MOLYBDOPHOSPHATE HETEROPOLYANIONS AND THEIR APPLICATION IN ELECTROCATALYSIS

Authors

  • Veronika V. Poltavets Днепропетровский национальный университет имени О. Гончара, Ukraine https://orcid.org/0000-0003-3386-3585
  • Mohammed E. A. Al-Shwaiyat Zarka University College, Al-Balqa Applied University, Zarka St. 30, Al-Salt, 19117 Jordan, Jordan
  • Tatyana А. Denisenko Днепровский национальный университет имени Олеся Гончара, Ukraine https://orcid.org/0000-0001-7755-9855
  • Andrii B. Vishnikin ДНУ им. О. Гончара, Ukraine
  • Ahmet M. Önal Middle East Technical University, Inönü Bulvari, 06531 Ankara, Turkey, Turkey

DOI:

https://doi.org/10.15421/081714

Keywords:

molybdophosphate heteropoly anions, electrocatalysis, modified electrode

Abstract

Polyoxometallates (POMs) are increasingly used as electrocatalysts for the determination of several types of species. Dawson and Keggin-type heteropoly anions are preferentially used in industry as catalysts. Properties of Dawson-type molybdophosphate heteropoly anions are discussed in the present review. Electrochemical behavior of Keggin- and Dawson-type molybdophosphate heteropoly anions has been reviewed. The oxidation-reduction potentials of electron reductions of the [P2Mo18O62]6– anion in solutions with various pH and in different media are cited. Special focus is made on methods of designing of electrodes modified by POMs. The most common deposition techniques of POMs include chemisorption, electrodeposition, encapsulation in polymers or sol–gels, and formation of hybrid POM–organic species. Advantages and disadvantages of various techniques are discussed. Modified electrodes are characterized by electrochemical stability, shifting of characteristic peaks and sensitivity to pH change.

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Published

2018-02-22

Issue

Vol. 25 No. 2 (2017): Bulletin of Dnipropetrovsk University. Series Chemistry

Section

Analytical Chemistry

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