Квантово-химическое исследование одноэлектронных реакций аква- и смешанолигандных комплексов хрома(ІІІ)
Abstract
С использованием метода DFT и поляризационного континуума исследована реакция Cr3+ + e- → Cr2+ в аква- и смешаннолигандных комплексах хрома (III). Показано, что вхождение во внутреннюю координационную сферу анионов органических кислот приводит к уменьшению скорости электровосстановления, но без структурных измененийDownloads
Published
2008-02-01
Issue
Section
Electrochemistry
License
Copyright (c) 2015 Дніпропетровський національний університет імені Олеся Гончара
This work is licensed under a Creative Commons Attribution 4.0 International License.
- Authors reserve the right of attribution for the submitted manuscript, while transferring to the Journal the right to publish the article under the Creative Commons Attribution License. This license allows free distribution of the published work under the condition of proper attribution of the original authors and the initial publication source (i.e. the Journal)
- Authors have the right to enter into separate agreements for additional non-exclusive distribution of the work in the form it was published in the Journal (such as publishing the article on the institutional website or as a part of a monograph), provided the original publication in this Journal is properly referenced
- The Journal allows and encourages online publication of the manuscripts (such as on personal web pages), even when such a manuscript is still under editorial consideration, since it allows for a productive scientific discussion and better citation dynamics (see The Effect of Open Access).