Sequential injection spectrophotometric determination of analgine in pharmaceutical formulations using 18-molybdo-2-phosphate heteropoly anion as chromogenic reagent

Authors

  • Mohammed Khair E. A. Al-Shwaiyat Zarka University college, Al-Balqa’ Apllied University, Jordan
  • Andriy B. Vishnikin Oles Honchar Dnipropetrovsk National University, Ukraine
  • Ludmila P. Tsiganok Oles Honchar Dnipropetrovsk National University, Ukraine
  • Ekaterina V. Kabashnaya Oles Honchar Dnipropetrovsk National University, Ukraine
  • Svetlana A. Khmelovskaya Oles Honchar Dnipropetrovsk National University, Ukraine
  • Vasil Andruch P.J. Šafarik University, Slovakia
  • Yaroslav R. Bazel P.J. Šafarik University, Slovakia
  • Hana Sklenářová Charles University, Czechia
  • Petr Solich Charles University, Czechia

DOI:

https://doi.org/10.15421/081301

Keywords:

analgine, 18-molybdo-2-phosphate, sequential injection analysis

Abstract

Simple, sensitive and selective sequential injection analysis (SIA) method for the analgine determination has been developed on the basis of fast reaction between analgine and 18-molybdo-2-phosphate heteropoly anion (18-MPA). Under found optimal conditions (0.01 M HCl, C(18-MPA) = 2 mmol/L) linear calibration curve was obtained over the range from 0.5 to 80 mg/L of analgine, and detection limit (S/N = 3) was 0.2 mg/L. The proposed SIA method has high sample throughput of 45 h-1 and small reagent consumption (0.08 mL). The procedure was successfully applied to the analysis of pharmaceuticals.           

Author Biographies

Mohammed Khair E. A. Al-Shwaiyat, Zarka University college, Al-Balqa’ Apllied University

           

Andriy B. Vishnikin, Oles Honchar Dnipropetrovsk National University

           

Ludmila P. Tsiganok, Oles Honchar Dnipropetrovsk National University

           

Ekaterina V. Kabashnaya, Oles Honchar Dnipropetrovsk National University

           

Svetlana A. Khmelovskaya, Oles Honchar Dnipropetrovsk National University

           

Vasil Andruch, P.J. Šafarik University

           

Yaroslav R. Bazel, P.J. Šafarik University

           

Hana Sklenářová, Charles University

           

Petr Solich, Charles University

           

References

Marcolino-Júnior, L.H., Sousa, R.A., Fatibello-Filho, O., Moraes, F.C. Flow-Injection spectrophotometric determination of dipyrone in pharmaceutical formulations using ammonium molybdate as chromogenic reagent. Anal. Lett., 2005, vol. 38, no. 14, p. 2315-2326.

Lima, J.L.F.C., Sá, S.M.O., Santos, J.L.M., Zagatto, E.A.G. Multi-pumping flow system for the spectrophotometric determination of dipyrone in pharmaceutical preparations. J. Pharm. Biomed. Anal., 2003, vol. 32, no. 4, p. 1011-1017.

Srivastava, M.K., Ahmad, S., Singh, D., Shukla, I.C. Titrimetric determination of dipyrone and paracetamol with potassium hexacyanoferrate(III) in an acidic medium. Analyst, 1985, vol. 110, p. 735-737.

Qureshi, S.Z., Saeed, A., Haque, S. Some observations on a simple method for the determination of novalgin in drug formulations with iron(III) – 1,10-phenanthroline. Microchem. J., 1990, vol. 41, no. 3, p. 362-365.

Qureshi, S.Z. Saeed, A., Hasan, T. Spectrophotometric determination of novalgin in tablets by use of potassium iodate. Talanta, 1989, vol. 36, no. 8, p. 869-871.

Sakiara, K.A., Pezza, L., Melios, C.B., Pezza, H.R., Moraes, M. Spectrophotometric determination of dipyrone in pharmaceutical preparations by using chromotropic acid. Il Farmaco, 1999, vol. 54, no. 9, p. 629-635.

Suarez, W.T., Pessoa-Neto, O.D., Vicentini, F.C., Janegitz, B.C., Faria, R.C., Fatibello-Filho, O. Flow Injection Spectrophotometric Determination of Dipyrone in Pharmaceutical Formulations Using Fe(III) as Reagent. Anal. Lett., 2011, vol. 44, no. 1-3, p. 340-348.

Zaporozhets, O.A., Krushinskaya, E.A., Lipkovskaya, N.A., Sukhan, V.V. Solid-phase reagent for analgin and ascorbic acid on the basis of a copper(II) complex with tetrabenzotetraazacyclohexadecine immobilized by adsorption on silica gel. J. Anal. Chem., 2001, vol. 56, no. 6, p. 524-529.

Morelli, B.J., Pharm. Biomed. Determination of binary mixtures of analgesic and spasmolytic drugs in pure and dosage forms by derivative spectrophotometry. Anal., 2003, vol. 33, no 3, p. 423-433.

Pradana Pérez, J.A., Alegría, J.S.D., Hernando, P.F., Sierra, A.N. Determination of dipyrone in pharmaceutical preparations based on the chemiluminescent reaction of the quinolinic hydrazide – H2O2 – vanadium(IV) system and flow injection analysis. Luminescence, 2011, vol. 27, no. 1, p. 45-50.

Zhao, L., Li, B., Zhang, Z., Lin, J.-M. Chemiluminescent flow-through sensor for automated dissolution testing of analgin tablets using manganese dioxide as oxidate. Sensors and Actuators, 2004, vol. 97, no. 2-3, p. 266-271.

Perez-Ruiz, T., Martinez-Lozano, C., Tomas, V., Carpena, J. Flow-injection fluorometric determination of novalgin in pharmaceutical preparations. Microchem. J., 1993, vol. 47, no. 3, p. 296-301.

Basáez, L.A., Periĉ, I.M., Jara, P.A., Soto, C.A., Contreras, D.R., Aguirre, C., Vanysek, P. Electrochemical and electrophoretic study of sodium metamizole. J. Chil. Chem. Soc., 2008, vol. 53, no. 3, p. 1572-1575.

Marcolino-Júnior, L.H., Bergamini, M.F., Teixeira, M.F.S., Cavalheiro, E.T.G., Fatibello-Filho, O. Flow injection amperometric determination of dipyrone in pharmaceutical formulations using a carbon paste electrode. Il Farmaco, 2003, vol. 58, no. 10, p. 999-1004.

Medeiros, E.P., Castro, S.L., Formiga, F.M., Santos, S.R.B., Araujo, M.C.U., Nascimento, V.B. A flow injection method for biamperometric determination of dipyrone in pharmaceuticals. Microchem J., 2004, vol. 78, no. 1, p. 91-96.

Pérez-Ruiz, T., Lozano, C.M., Tomás, V. Flow-injection determination of Novalgin using amperometric detection at a glassy carbon electrode. J. Pharm. Biomed. Anal., 1994, vol. 12, no. 9, p. 1109-1113.

Teixeira, M.F.S., Marcolino-Júnior, L.H., Fatibello-Filho, O., Dockal, E.R., Cavalheiro, E.T.G. Voltammetric determination of dipyrone using a N,N’-ethylenebis(salicylideneaminato)oxovanadium(IV) modified carbon-paste electrode. J. Braz. Chem Soc., 2004, vol. 15, no. 6, p. 803-808.

Senyuva, H.Z., Aksahin, I., Ozcan, S., Kabasakal, B.V. Rapid, simple and accurate liquid chromatography–diode array detection validated method for the determination of dipyrone in solid and liquid dosage forms. Anal. Chim. Acta., 2005, vol. 547, no. 1, p. 73-77.

Loginova, L.P., Konovalova, O.Yu. Test films for test-determinations on the base of reagents, immobilized in gelatinous gel. Talanta, 2008, vol. 77, no. 2, p. 915-923.

Ruzicka, J. Flow injection analysis. 2nd Ed., N.Y.: J. Wiley, 1988, 498 p.

Ruzicka, J., Marshall, G.D. Sequential injection: a new concept for chemical sensors, process analysis and laboratory assays. Anal. Chim. Acta., 1990, vol. 237, p. 329-343.

Daniel, D., Gutz, I.G.R. Electronic micropipettor: A versatile fluid propulsion and injection device for micro-flow analysis. Anal. Chim. Acta., 2006, vol. 571, no. 2, p. 218-227.

Huang, Y.-M., Zhang, C., Zhang, X.-R., Zhang, Z.-J. A novel chemiluminescence flow-through sensor for the determination of analgin. Fres. J. Anal. Chem., 1999, vol. 365, no. 4, p. 381-383.

Calatayud, J.M. Flow Injection Analysis of Pharmaceuticals, London: Taylor & Francis, 1996, 315 p.

Albuquerque, J.S., Silva, V.L., Araújo, A.N., Montenegro, M.S.B.S.M. Determination of dipyrone in pharmaceutical products by flow injection analysis with potentiometric detection. Anal. Sci., 2003, vol. 19, no. 5, p. 691-694.

Boni, A.C., Wong, A., Dutra, R.A.F., Sotomayor, M.D.P.T. Cobalt phthalocyanine as a biomimetic catalyst in the amperometric quantification of dipyrone using FIA. Talanta, 2011, vol. 85, no. 4, p. 2067-2073.

Weinert, P.L., Fernandes, J.R., Pezza, L., Pezza, H.R. Flow-Injection Spectrophotometric Determination of Novalgin in Pharmaceuticals Using Micellar Medium. Anal. Sci., 2007, vol. 23, no. 12, p. 1383-1389.

Petrushina, G.A., Tsiganok, L.P., Vishnikin, A.B. Spectrophotometric determination of ascorbic acid by P2Mo18O626-. Ukr. Khim. Zhurn., 2010, vol. 36, no. 4, p. 116-122.

Bulatov, A.V., Petrova, A.V., Vishnikin, A.B., Moskvin, A.L., Moskvin, L.N. Stepwise injection spectrophotometric determination of epinephrine. Talanta, 2012, vol. 96, p. 62-67.

Vishnikin, A.B., Sklenařova, H., Solich, P., Petrushina, G.A., Tsiganok, L.P. Determination of ascorbic acid with Wells-Dawson type molybdophosphate in sequential injection system. Anal. Lett., 2011, vol. 44, no. 1-3, p. 514-527.

Vishnikin, A.B., Al-Shwaiyat, M.K.E.A., Petrushina, G.A., Tsiganok, L.P., Andruch, V., Bazel, Ya.R., Sklenarova, H., Solich, P. Highly sensitive sequential injection determination of p-aminophenol in paracetamol formulations with 18-molybdodiphosphate heteropoly anion based on elimination of Schlieren effect. Talanta, 2012, vol. 96, p. 230-235.

Saeed, A. Spectrophotometric determination of novalgin in pharmaceutical preparations by the molybdenum blue method. Indian J. Pharm. Sci., 1998, vol. 60, no. 3, p. 161-163.

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Published

2014-03-12

Issue

Vol. 21 No. 19 (2013): Bulletin of Dnipropetrovsk University. Series Chemistry

Section

Analytical Chemistry

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