Substituent and environment influence on analytical properties of associates of xanthene dyes with polyhexamethyleneguanidine chloride

Authors

  • Tatiana S. Chmilenko Oles Honchar Dnipropetrovsk National University, Ukraine
  • Lidiya A. Ivanitsa Oles Honchar Dnipropetrovsk National University, Ukraine
  • Fedor A. Chmilenko Oles Honchar Dnipropetrovsk National University, Ukraine

DOI:

https://doi.org/10.15421/081320

Keywords:

trioxyfluorone, spectrophotometry, polyhexamethyleneguanidine chloride, polyelectrolyte, ionisation constant, aggregation

Abstract

The interaction of 5 anionic xanthene dyes – 9-R-2,3,7-trihydroxy-6-fluorones (ТОF) with cationic polyelectrolyte (PE) – polyhexamethyleneguanidine chloride (PHMG) has been studied by the optical spectroscopy in a concentration range where PHMG has a polyelectrolyte effect. Hammet σ-constants were calculated. The correlations between structure of ТОF and shift of protolytic equilibrium in aqueous-polyelectrolyte solutions were established. Influence of рН, concentration of the ethanol, components ratio in the system PHMG-TOF on the character of the interaction of cationic PE with ТОF and value of the analytical signal were studied based on absorption spectra. The results were compared to those obtained in water solutions. 

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Published

2014-03-28

Issue

Vol. 21 No. 20 (2013): Bulletin of Dnipropetrovsk University. Series Chemistry

Section

Analytical Chemistry

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