Spectrophotometric determination of ascorbic acid by using bismuth containing 18-molybdodiphosphate

Authors

  • Galina A. Petrushina Dnipropetrovsk State Agrarian University, 25, Voroshylova Str., Dnipropetrovsk, 49600, Ukraine
  • Juliya V. Mekh Oles Honchar Dnipropetrovsk National University, 72, Gagarin Ave., Dnipropetrovsk 49010, Ukraine
  • Ludmila P. Tsiganok Oles Honchar Dnipropetrovsk National University, 72, Gagarin Ave., Dnipropetrovsk 49010, Ukraine
  • Andriy B. Vishnikin Oles Honchar Dnipropetrovsk National University, 72, Gagarin Ave., Dnipropetrovsk 49010, Ukraine
  • Darya V. Podgornaya Chemical and Ecological Lyceum of Dnipropetrovsk City Council, 14B, Heroes of Stalingrad Str., Dnipropetrovsk, 49069, Ukraine

DOI:

https://doi.org/10.15421/081405

Keywords:

Wells-Dawson heteropoly complex, 18-molybdodiphosphate, heteropoly blue, bismuth, ascorbic acid

Abstract

Reactions of formation and reduction of bismuth substituted 18-molybdophosphate (18-MBPC) with ascorbic acid (Asc) have been investigated. 18-MBPC is reduced by Asc in the presence of Bi(III) ions at the ratio of Asc:18-MBPC 1:1 and 2:1 with formation of, respectively, two- and four-electron reduced heteropoly blues. Their spectra are similar to the spectra of metalsubstituted heteropoly blues with Keggin structure and have an absorption maximum at 690 nm. Selective, rapid and simple method was developed for the determination of Asc. Benefits of using the 18-MPBC as analytical reagent are high sensitivity and rate of reduction rate, including the behavior in acid solutions. The limit of detection was of 2.6·10–6 mol/l (l = 1 cm), and ε was of 1.15·104 mol–1·l·cm–1.

Author Biography

Juliya V. Mekh, Oles Honchar Dnipropetrovsk National University, 72, Gagarin Ave., Dnipropetrovsk 49010

M.S. in Chemistry, PhD Student

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Published

2014-12-02

Issue

Vol. 22 No. 1 (2014): Bulletin of Dnipropetrovsk University. Series Chemistry

Section

Analytical Chemistry

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Copyright (c) 2014 Oles Honchar Dnipropetrovsk National University

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