Cover Image

Ionexchanged film materials on basis of oligoepichlorohydrined epoxide and piperazine

Konstantyn E. Varlan, Svetlana A. Plotichkina, Aleksandra L. Kuzmenko

Abstract


The film materials with ion-exchanged properties on the basis of the polymer, obtained by condensation of oligoepichlorohydrined epoxide and piperazine with the subsequent chemical modification have been synthesized. Compounds which have different thermodynamic affinity with the polymer and each other have been used as modifiers. It has been shown that the possibility of overcoming the lack of compatibility of the components by selection of the order of their combination. The result of the combination can be predicted by the Hildebrand parameter values of the ingredients, intermediate products and prepolymers based on them. The properties of synthesized materials can be adjusted by selection of combinations of chemical modifiers: toluilenediisocyanate, epoxyed soybean oil and tetraethoxysilane.

Keywords


ion-exchanged film material; epoxide; piperazine; Hildebrand parameter; modification

References


Andriianova, M. V. Synthesis and research of properties of polymeric quaternary ammonium salts for ion-conducting materials. PhD thesis. Ukrainian State University of Chemical Technology, Dnipropetrovsk, 2009. [in Russian]

Berezina, N. P. Synthetic exchange membranes. Soros educational journal, 2000, vol. 6, no. 9, p. 37-42. [in Russian]

Smitha, B., Sridhar, S., Khan, A. A. Solid polymer electrolyte membranes for fuel cell application: a review. J. Membr. Sci., 2005, no 1‒2, Р. 10‒26.

Varlan, K. Е., Serdуuk, D. V. Crosslinking in the diglycidyl ether oligoepichlorhydrin-piperazine. Visn. Dnipropetr. Univ.: Khim, 2013, vol. 21, no. 20, p. 118‒123. [in Russian]

Askadskii A. A., Kondraschenko V. I. Komp'yuternoye materialovedeniye polimerov. Vol. 1. Atomno-molekulyarnyy uroven'. Moscow: Nauchnyy mir, vol. 1,1999, 544 p. [in Russian]

Shvarts, A. H., Dynzburh, B. N., Sovmeshcheniye kauchukov s plastmassami i sinteticheskimi smolami. Moscow: Khimia, 1972, 224 p. [in Russian]

Entsiklopediya polimerov: in 3 vol. Ed.: V. A. Kargin. Мoscow: Sovetskaia entsyklopedyia, 1972, vol. 1, 1224 р. [in Russian]

Kalinina, L. S., Motoryna, N. I., Nikitina N. A., Khachapurydze, N. A. Analiz kondensatsionnykh polimerov. Moscow: Khimia, 1984, 296 p. [in Russian]




DOI: http://dx.doi.org/10.15421/081413

Refbacks

  • There are currently no refbacks.




Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.

______________________________________________________
BULLETIN OF DNIPROPETROVSK NATIONAL UNIVERSITY
eISSN: 2313-4984 | pISSN: 2306-871X
Contact:chem.dnu@gmail.com
The journal publishes research papers on terms: Creative Commons Attribution 4.0 International License
Founder: Oles Honchar Dnipropetrovsk National University