Obtaining for the first time in USSR heavy water samples of A. I. Brodskii’s laboratory in the country

Valerij S. Kovalenko, Viktor F. Vargalyuk, Nadiia V. Stets


This article is devoted to the significant event for national science – obtaining of initial portions of heavy (deuterium) water. The receiving of heavy water by multiple-stage electrolysis was carried out by the group of Dnipropetrovsk scientists under the supervision of professor A I. Brodskii in summer 1934. The article dwells upon the prerequisites of discovery of heavy-hydrogen water, it shows the role of academician A. I. Brodskii in the organization and provision of scientific supervision of investigations. The authors adduce features of the experimental method used by the Dnipropetrovsk scientists (the multiple-stage electrolysis) and also peculiarities of methods of control over the process of water enrichment by the heavy Hydrogen isotope (interferometric, differential and picnometric). The article tells about history of creation of experimental and semi-industrial equipment for obtaining heavy water. It accentuates the importance of Brodskii group’s success for the further development of research in the area of isotope chemistry and nuclear physics and also his role in solving of nuclear problem.


academician A. I. Brodskii; obtaining of heavy water; Hydrogen; Deuterium; isotopes; electrolysis


Gordienko, L. (2004). [Discoverer of heavy water (to 110th anniversary of academician Alexandr Brobskii’s birth)]. In Ukrainian history and culture-2005: calendar-yearbook (pp. 191–196). – Kiev, Ukraine: Ukr. vidavn. spilka (in Ukrainian).

Brodskii, A. I. (1936). [The receiving of heavy water in USSR]. Tehnika – Technology, 6 June. Arhiv IFH NAN Ukrayin  Archives of Physical Chemistry Institute of Academy of Sciences of Ukraine, f.2, desc.2 (in Russian).

[The first stage of work is over]. (1934). Zvezda – Star, 26 July; Archives of Physical Chemistry Institute of Academy of Sciences of Ukraine, f. 2, desc. 2 (in Russian).

Mendeleev, I. D. (1935). [Huge victory of Soviet science. Receiving of heavy water ]. Vechernyaya krasnaya gazeta – Evening red newspaper – 14 Dec. Museum of History of Physical Chemistry Institute, f. 2, st. 2 (in Russian).

[The obtaining of heavy water in USSR]. (1936). Nauka i tehnika. – Science & Technology, (9); (1967). Nauka i zhizn – Science & life, (11), 76 (in Russian).

Volkov, V. A., & Trifonov, D. N. (1984). [Receiving of the first laboratory amounts of native heavy water by A. I. Brodskii (to 50th anniversary of the beginning of production of heavy water in USSR)]. In Questions of history of natural science and technology, (1), 75–78 (in Russian).

Burmistr, M. V. (1999). [Easy destiny of «heavy water»]. Dnipropetrovsk, Ukraine: Dnepr. pravda – Dnipr. truth, 7 Sept. (in Russian).

Aston, F. (1948). [Mass-spectrums and isotopes]. Moscow, USSR: Izdatinlit (in Russian).

Brodskii, A. I. (1957). [Chemistry of isotopes]. Moscow, USSR: Izdatel. AN SSSR (in Russian).

Lewis, G., & Macdonald, R. (1933). Concentration of H2 isotope. J. Chem. Phys., 1, 341.

Shapoval, I. M. (1982) [Near sources of heavy water]. In Sources of Pridniprovya. Tells about scientists. Kiev, USSR: Radyan. pismen. (in Ukrainian).

Brodskii, A. I. (1950). [20th anniversary of L. V. Pisarzhevskii’s Physical Chemistry Institute of Academy of Sciences of Ukraine]. In 20th years of L. V. Pisarzhevskii’s Physical Chemistry Institute. Kiev, USSR (in Russian).

Yatsimirskiy, K. B. (Ed.). (1977). [Development of physical chemistry in Academy of Science of Ukrainian SSR]. Kiev, USSR: Nauk. dumka (in Russian).

[Ukrainian State University of Chemistry and Technology. The History 19302000]. (2000). Dnipropetrovsk, Ukraine (in Russian).

Chernikov, O. (1976). [Storming the heath of «Mystery»]. Prapor yunosti – The banner of youth, 21 May (in Ukrainian).

Goldshmidt, B. (1964). [Nuclear problem]. Moscow, USSR: Atomizdat (in Russian).

Brodskii, A. I., Aleksandrovich, V. A., Slutskaya, M. M., & Sheludko, M. K. (1934). [The concentrating of heavy water]. Reports of Academy of Sciences of USSR, 3(8/9), 615–619 (in Russian).

Pohodenko, V. D. (1988). [Alexandr I. Brodskii]. Kiev, Ukraine: Nauk. dumka (in Russian).

Andreev, B. M., Zalʹvanskyj, Ja. D., & Katalʹnykov, S. H. (1987). [The heavy isotopes of Hydrogen in the nuclear technology]. Moscow, USSR: Enerhoatomyzdat (in Russian).

Temkin, M. I. Not easy water. Copyright by Foxit Software Company, 20042007. – Retrieved from http://temkin-76.ucoz.ru/ (in Russian).

Brodskii, A. I. (1974). [Selected works (Vols. 1–2)] – Kiev, USSR: Nauk. dumka (in Russian).

Brodskii, A. I., Aleksandrovich, V. A., & Skarre, O. K. (1937). [The fractionating of Oxygen’s isotopes by distillation of water]. J. Phys. Chem., 10(3), 538–539 (in Russian).

Brodskii, A. I. (1936). [The obtaining of heavy water. Text of radio-lecture]. Museum of history of Physical Chemistry Institute, f. 2, desc. 2 (in Russian).

Petrosyants, A. M. (1967). [Nuclear energetics and peaceful use of nuclear energy]. In Development of physics in USSR, vol. 2, (pp. 300–326). Moscow, USSR: Nauka (in Russian).

Kovalenko, V. S., Chmilenko, F. O., Vargalyuk, V. F. (2011). [The history of Chemical Faculty of Dnipropetrovsk National University (scientific directions, events and people)]. Dnipropetrovsk, Ukraine: Vid-vo DNU (in Ukrainian).

[Materials about connections of Physical Chemistry Institute with higher education institutions (1951–1962 years)]. Archive Studies Institute of V. I. Vernadskii’s Ukrainian National Library, f. 7, desc. 3, case 9 (in Ukrainian).

DOI: http://dx.doi.org/10.15421/081510


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