Effect of polyelectrolytes on PbO2 electrodeposition

Tatiana V. Luk’yanenko, Larysa V. Dmitrikova, Natalia I. Krivonosova, Alexander B. Velichenko


Kinetic regularities of the electrodeposition of lead dioxide from electrolytes containing polyelectrolytes Drimax 1235 and Magnafloc manufactured by Ciba have been investigated. It was determined that the inhibition of the reaction of electrooxidation of Pb2+ with the decrease of a transfer coefficient without the changing of the mechanism of the process occurs in the presence of polyelectrolytes as additives in the deposition electrolyte. Observed effects depend upon the nature of the polyelectrolyte and probably caused by blocking of active sites on the surface of the growing oxide by adsorbed polyelectrolyte molecules. The use of polyelectrolytes as additives leads to a change in the catalytic activity of obtained materials in the reactions of oxygen evolution and oxidation of 4-chlorophenol.


electrodeposition; polyelectrolyte; anode materials; electrocatalytic activity


Feng, J., & Johnson, D. C. (1991). Electrocatalysis of anodic oxygen-transfer reactions: titanium substrates for pure and doped lead dioxide films. J. Electrochem. Soc., 138(11), 3328–3337.

LaCourse, W. R., Hsiao, Y.-L., & Johnson, D. C. (1989). Electrocatalytic oxidation at electrodeposited bismuth(III)-doped beta-lead dioxide film electrodes. J. Electrochem. Soc., 136 (12), 3714–3719.

Shao, Z., Yi, B., Zhang, X., & Zhang, E. (1997). Preparation of PbO2/Ti plate electrode. Dianhuaxue, 3(3), 319–324.

Shmychkova, O., Luk’yanenko, Т., Velichenko, A., Meda, L., & Amadelli, R. (2013). Bi-doped PbO2 anodes: Electrodeposition and physico-chemical properties. Electrochim. Acta, 111, 332–338.

Shmychkova, O., Luk'yanenko, T., Velichenko, A., & Amadelli, R. (2013). Electrodeposition of Ce-doped PbO2. J. Electroanal. Chem., 706, 86–92.

Velichenko, A. B., Amadelli, R., Benedetti, A., Girenko, D. V., Kovalyov, S. V., & Danilov, F. I. (2002). Electrosynthesis and physicochemical proerties of PbO2 films. J. Electrochem. Soc., 149 (9), C445-C449.

Shmychkova, O., Luk’yanenko, Т., Amadelli, R., & Velichenko, A. (2014). Рhysico-chemical properties of PbO2-anodes doped with Sn4+ and complex ions. J. Electroanal. Chem., 717-718, 196–201.

Trasatti, S., & Lodi, G. (1981) Oxygen and chlorine evolution at conductive metallic oxides. Electrodes of conductive metallic oxides. Part B. Amsterdam: Elsevier, 521–626.

Amadelli, R., Samiolo, L., De Battisti, A., & Velichenko, A. (2011). Electrooxidation of Some Phenolic Compounds by Electrogenerated O3 and by Direct Electrolysis at PbO2 Anodes. J. Electrochem. Soc., 158, P87–P92.

Amadelli, R., & Velichenko, A. (2001). Lead Dioxide Electrodes for High Potential Anodic Processes. J. Serbian Chemical Society, 66, 835–845.

Azzam, M. O., Al-Tarazi, M., & Tahboub, Y. (2000). Anodic destruction of 4-chlorophenol solution. J. Hazardous Materials, B75, 99–113.

Gherardini, L., Michaud, P. A., Panizza, M., Comninellis, Ch., & Vatistas, N. (2001). Electrochemical oxidation of 4-chlorophenol for wastewater treatment. J. Electrochem. Soc., 148 (6), D78–D82.

DOI: http://dx.doi.org/10.15421/081603


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