DOI: https://doi.org/10.15421/0817260203

INTERACTION OF THE LANTHANA, YTTRIA WITH SAMARIA AT TEMPERATURE 1500 °C

Olga. V. Chudinovych, Elena R. Andrievskaya, Janna D. Bogatyryova, Oleksandr I. Bukov

Abstract


Using the methods of physicochemical analysis (XRD, petrography, SEM, X–ray microprobe analysis) phase equilibria were firstly investigated in the ternary system La2O3–Y2O3–Sm2O3 at 1500 °C.The samples of different compositions have been prepared from nitrate acid solutions by evaporation, drying, and calcinations at 1100 аnd 1500 °C. The XRD used the powder method of sampling at room temperature (CuКa irradiation). The crystal-optic characteristics of the obtained phases were determined under polarized microscope “МІН-8”. The refraction indexes were measured in immersion liquids (solution of arsenic tribromide in methylene iodide or alloys of sulfur with selenium) with accuracy ± 0.02. The solid solutions based on various polymorphous forms of constituent phases and ordered phase with a structure of the perovskite-type of LaYO3 were revealed in the system. The boundaries of mutual solubility and concentration dependences the lattice parameters for all phases have been determined. The isothermal sections of the phase diagrams for the La2O3–Y2O3–Sm2O3 systems at 1500 °C are characterized by the presence of one three-phase (B + C + R), four single-phase (A-La2O3 (Sm2O3), B-La2O3 (Sm2O3), R, C-Y2O3) and two-phase (A + B, B + R, C + R, B + C) regions.

Keywords


lanthana; yttria, samaria; phase equilibria; isothermal section; solid solutions; lattice parameters of the unit cells; functional and structural ceramics

References


Бібліографічні посилання

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