RAPID, HIGHLY SENSITIVE AND SELECTIVE SPECTROPHOTOMETRIC DETERMINATION OF CADMIUM(II) AS AN ION ASSOCIATE OF TETRAIODOCADMIATE(II) WITH ASTRA PHLOXINE

Authors

  • Mehyeddine Hedjazi Oles Honchar Dnipro National University, Algeria
  • Andriy B. Vishnikin Oles Honchar Dnipro National University, Ukraine
  • Svetlana N. Khudyakova Oles Honchar Dnipro National University,

DOI:

https://doi.org/10.15421/081930

Keywords:

cadmium determination, ion associate, Astra Phloxine, spectrophotometry, Wood`s alloy, mine water

Abstract

A very simple, rapid, highly sensitive and selective non-extractive spectrophotometric method for the determination of trace amounts of cadmium(II) has been proposed. It is based on the formation of ion association complex (IA) between iodide complex of cadmium Cd(II) [CdJ42-] and polymethine dye Astra Phloxine FF. The color of the solution changes from red to red-purple. The color of the IA develops completely at temperature less than 18 oC after 5-10 minutes after mixing of reagents and remains constant over several hours. Opitmal concentrations of HCl, AP and KJ are 0.07–0.13 M, 1.2×10-5 M and 6×10-3 M, respectively. The molar absorptivity of the IA is 6.5×104 mol-1 L cm-1. The calibration graph is linear between 1×10-7 and 3×10-6 mol L-1 of cadmium (II). The limit of detection is 5×10-8 mol L-1 (l = 5 cm, 0.006 mg L-1). A large excess of over 50 cations, anions and some common complexing agents do not interfere with the determination. The method was successfully applied in the determination of cadmium in Wood`s alloy and mine water.

Author Biographies

Mehyeddine Hedjazi, Oles Honchar Dnipro National University

PhD student of Analytical Chemistry Department of DNU

Andriy B. Vishnikin, Oles Honchar Dnipro National University

Head of Analytical Chemistry Department h-index (SCOPUS) = 10

Svetlana N. Khudyakova, Oles Honchar Dnipro National University

Docent of Analytical Chemistry Department of DNU

References

Škrlíková, J., Andruch, V., Sklenářová, H., Solich, P., Balogh, I. S., Billes, F. (2011). A novel non-extractive sequential injection procedure for determination of cadmium. Anal. Lett., 44(1–3), 431–445. https://doi.org/10.1080/00032719.2010.500783

da Silva, J.B.B., Borges, D.L.G., da Veiga, M.A.M.S., Curtius, A.J., Welz, B. (2003). Talanta, 60(5), 977–982. https://doi.org/10.1016/S0039-9140(03)00182-6

Shirkhanloo, H., Ghazaghi, M., Mousavi, H.Z. (2016). Cadmium determination in human biological samples based on trioctylmethyl ammonium thiosalicylate as a task-specific ionic liquid by dispersive liquid–liquid microextraction method. J. Molec. Liquids, 218, 478–483. https://doi.org/10.1016/j.molliq.2016.02.035

Fırat, M., Bakırdere, S., Fındıkoğlu, M. S., Kafa, E. B., Yazıcı, E., Yolcu, M., Turak, F. (2017). Determination of trace amount of cadmium using dispersive liquid-liquid microextraction-slotted quartz tube-flame atomic absorption spectrometry. Spectrochim. Acta B, 129, 37–41. https://doi.org/10.1016/j.sab.2017.01.006

Gao, L., Chen, F., Yang, H.Y., Yan, G.H., Zhong, G.X. (2012). Determination of Cd(II) in water samples by summable spectrophotometry of positive-negative peaks after cloud point extraction. In Advanced Materials Research, 573–574, 48–52. https://doi.org/10.4028/www.scientific.net/AMR.573-574.48

de Castro Maciel, C. J., Miranda, G.M., de Oliveira, D.P., de Siqueira, M.E.P., Silveira, J.N., Leite, E.M.A., da Silva, J.B.B. (2003). Determination of cadmium in human urine by electrothermal atomic absorption spectrometry. Anal. Chim. Acta, 491 (2), 231–237. https://doi.org/10.1016/S0003-2670(03)00820-1

Kendüzler, E., Türker, A.R. (2005). Determination of trace cadmium in waters by flame atomic absorption spectrophotometry after preconcentration with 1‐nitroso‐2‐naphthol‐3, 6‐disulfonic acid on Ambersorb 572. Annali di Chimica: Journal of Analytical, Environmental and Cultural Heritage Chemistry, 95 (1‐2), 77–85. https://doi.org/10.1002/adic.200590009

Welz, B., Xu, S., Sperling, M. (1991). Flame atomic absorption spectrometric determination of cadmium, cobalt, and nickel in biological samples using a flow injection system with on-line preconcentration by co-precipitation without filtration. Applied spectroscopy, 45(9), 1433–1443. https://doi.org/10.1366%2F0003702914335625

Zougagh, M., de Torres A. G., Pavon J. C. (2002). Determination of cadmium in water by ICP-AES with on-line adsorption preconcentration using DPTH-gel and TS-gel microcolumns. Talanta, 56 (4), 753–761. https://doi.org/10.1016/S0039-9140(01)00605-1

Marguí, E., Queralt, I., Hidalgo, M. (2013). Determination of cadmium at ultratrace levels in environmental water samples by means of total reflection X-ray spectrometry after dispersive liquid–liquid microextraction. J. Anal. Atomic Spectrometry, 28(2), 266–273. https://doi.org/10.1039/C2JA30252G

Watanabe, H., Ohmori, H. (1979). Dual-wavelength spectrophotometric determination of cadmium with cadion. Talanta, 26 (10), 959–961. https://doi.org/10.1016/0039-9140(79)80133-2

Nagalaxmi, B.N., Viswanatha, C., Reddy, K.R., Chandrasekhar, K.B., Donappa, N. (2015). Determination of trace amount of Cd(II) by using a chromogenic reagent diacetylmonoxime-3-amino-4-hydroxy benzoyl hydrazone (DMAHBH) with UV-visible spectrophotometry. European Reviews of Chemical Research, (2), 104–111. https://doi.org/10.13187/ercr.2015.4.104

Di Nezio, M. S., Palomeque, M. E., Band, B. S. F. (2005). Automated flow-injection method for cadmium determination with pre-concentration and reagent preparation on-line. Química Nova, 28 (1), 145–148. http://dx.doi.org/10.1590/S0100-40422005000100025

Jaikrajang, N., Kruanetr, S., Harding, D. J., Rattanakit, P. (2018). A simple flow injection spectrophotometric procedure for iron (III) determination using Phyllanthus emblica Linn. as a natural reagent. Spectrochim. Acta A, 204, 726–734. https://doi.org/10.1016/j.saa.2018.06.109

Vishnikin, A.B., Al-Shwaiyat, M.E.A., Okovytyy, S.I., Chernavskaya, A.Yu., Hedjazi, M. (2018). Analytical effects based on interaction of organic dyes with heteropoly anions, anionic metal complexes and cationic polyelectrolytes. In «Scientific developments and achievements». London: Sciemcee Publishing, 2018. – P. 181–208.

Vishnikin, A. B., Al-Shwaiyat, M. K. E., Bazel, Ya. R., Andruch, V. (2007). Rapid, sensitive and selective spectrophotometric determination of phosphate as an ion associate of 12-molybdophosphate with Astra Phloxine. Microchim. Acta, 159 (3-4), 371–378. https://doi.org/10.1007/s00604-007-0754-7

Lavra, V., Bazel, Y., Badida, M., Andruch, V. (2015). Liquid–liquid microextraction and spectrophotometric determination of anionic surfactants using Astra Phloxine FF. Int. J. Environ. Anal. Chem., 95 (3), 217–224. https://doi.org/10.1080/03067319.2014.1002488

Vishnikin, A.B. (2005). Novel indirect spectrophotometric methods for determination of phosphate and arsenate using polyoxometalates and micellar medium. J. Molec. Liquids, 118 (1-3), 51–55. https://doi.org/10.1016/j.molliq.2004.07.012

Khudyakova, S. N., Vishnikin, A. B., Smityuk, N. M. (2018). A highly selective and sensitive colorimetric chemosensor based on polyurethane foam impregnated with 3-methyl-2,6-dimercapto-1,4-thiopyrone for on-site preconcentration and determination of palladium(II). Int. J. Environ. Anal. Chem., 98(13), 1253–1273. https://doi.org/10.1080/03067319.2018.1544634

Chmilenko, F.A., Khudyakova, S.N. (2013). Sorption preconcentration and separation of Palladium(II) and Platinum(IV) for visual test and densitometric determination. J. Anal. Chem., 68 (5), 409–416.

Chmilenko, F.A., Khudyakova, S.N. (2010). Sorption-colorimetric and test determination of osmium in alloys and concentrates. J. Anal. Chem., 65 (9), 907–911. https://doi.org/10.1134/S1061934810090042

Amin, A.S. (2001). Spectrophotometric determination of cadmium using thiazolylazo chromogenic reagents in the presence of triton X-100: Application in environmental samples. Anal. Lett., 34 (1), 163–176. https://doi.org/10.3329/jce.v25i0.7233

Garcia, I. L., Navarro, P., Cordoba, M. H. (1988). Manual and FIA methods for the determination of cadmium with malachite green and iodide. Talanta, 35 (11), 885–889. https://doi.org/10.1016/0039-9140(88)80207-8

Parikh, K. S., Patel, R. M., Patel, K. N. (2009). New spectrophotometric method for determination of cadmium. E-Journal Chem., 6, S496–S500. http://dx.doi.org/10.1155/2009/219736

Shar, G. A., Bhanger, M. I. (2003). Spectrophotometric determination of metal complexes of 1-(2 pyridylazo)-2-naphthol in micellar medium. J. Chem. Soc. Pakistan, 25 (1), 28–33.

Hashem, E. Y. (2002). Spectrophotometric studies on the simultaneous determination of cadmium and mercury with 4-(2-pyridylazo)-resorcinol. Spectrochim. Acta A, 58 (7), 1401–1410.

https://doi.org/10.1016/S1386-1425(01)00590-X

Bulgariu, L., Bulgariu, D., Sarghie, I. (2005). Spectrophotometric determination of cadmium(II) using p,p′‐dinitro‐SYM‐diphenylcarbazid in aqueous solutions. Anal. Lett., 38 (14), 2365–2375. https://doi.org/10.1080/00032710500316597

Ahmed, M. J., Chowdhury, M. T. I. (2004). A simple spectrophotometric method for the determination of cadmium in industrial, environmental, biological and soil samples using 5,7-dibromo-8-hydroxyquinoline. Anal. Sci., 20, 987–990.

https://doi.org/10.2116/analsci.20.987

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Published

2020-01-22

Issue

Vol. 27 No. 2 (2019): Journal of Chemistry and Technologies

Section

Analytical Chemistry

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