RESEARCH OF TECHNOLOGICAL PROPERTIES OF SPINEL PIGMENTS IN THE FE-Al-Mg-O SYSTEM.

Authors

  • Liliya A. Frolova Ukrainian State University of Chemical Technology http://orcid.org/0000-0001-7970-2264
  • Tetyana E. Butyrina Ukrainian State University of Chemical Technology
  • Alexander V. Zaichuk Ukrainian State University of Chemical Technology

DOI:

https://doi.org/10.15421/082032

Keywords:

pigments, color, color formation, spinel, extract pH, potential

Abstract

Two groups of pigments were obtained by coprecipitation in the Fe-Al-Mg-O system. With the help of experimental studies, the influence of cations of chromophores and heat treatment on the color tone, color purity, anti-corrosion properties of pigments in the Fe-Al-Mg-O system has been established, which allows further targeted synthesis of pigments in beige, red and yellow colors. It is shown that the main technological properties of pigments are determined by the anionic and cationic composition. Color characteristics are determined by the cation occupying a tetrahedral position in the crystal lattice. For all considered systems, an increase in covalence after heat treatment leads to a shift in color to the long-wavelength region of the spectrum and to an increase in color intensity. The anticorrosive properties of pigments are largely determined by the hydrolysis of the formed compounds. The protective effect is mainly determined by the slowing down of the anodic process. In this case, anions containing aluminum atoms accelerate corrosion processes.

 

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Published

2021-01-10