• Liliya A. Frolova Ukrainian State University of Chemical Technology, Ukraine
  • Tetyana E. Butyrina Ukrainian State University of Chemical Technology, Ukraine
  • Alexander V. Zaichuk Ukrainian State University of Chemical Technology, Ukraine



pigments, color, color formation, spinel, extract pH, potential


Two groups of pigments were obtained by coprecipitation in the Fe-Al-Mg-O system. With the help of experimental studies, the influence of cations of chromophores and heat treatment on the color tone, color purity, anti-corrosion properties of pigments in the Fe-Al-Mg-O system has been established, which allows further targeted synthesis of pigments in beige, red and yellow colors. It is shown that the main technological properties of pigments are determined by the anionic and cationic composition. Color characteristics are determined by the cation occupying a tetrahedral position in the crystal lattice. For all considered systems, an increase in covalence after heat treatment leads to a shift in color to the long-wavelength region of the spectrum and to an increase in color intensity. The anticorrosive properties of pigments are largely determined by the hydrolysis of the formed compounds. The protective effect is mainly determined by the slowing down of the anodic process. In this case, anions containing aluminum atoms accelerate corrosion processes.



Zhang, S., Jiang, W., Li, Y., Yang, X., Sun, P., Liu, F., Lu, G. (2019). Highly-sensitivity acetone sensors based on spinel-type oxide (NiFe2O4) through optimization of porous structure.Sensors and Actuators B: Chemical, 291, 266-274.

Zhou, T. Cao, S., Zhang, R., Tu, J., Fei, T., Zhanget, T. (2019). Effect of Cation Substitution on the Gas-Sensing Performances of Ternary Spinel MCo2O4 (M= Mn, Ni, and Zn) Multishelled Hollow Twin Spheres. ACS applied materials & interfaces, 11(31), 28023–28032.

Belyi, Y. I., Zaichuk, A. V. (2005). Ceramic pigments for producing black glazes. Glass and Ceramics, 62(9-10), 290–292.

Yan, J., Huang, J., Zhang, T., Tian, H., Yu, J., Zhang, L., Zhang, Y. (2019). Investigation of the microstructure, cation distribution and optical properties of nanoscale NixMg1-xAl2O4 spinel pigments. Ceramics International, 45(11), 14073–14083.

Aruchamy, K., Nagaraj, R., Manohara, H. M., Nidhi, M. R., Mondal, D., Ghosh, D., & Nataraj, S. K. (2020). One-step green route synthesis of spinel ZnMn2O4 nanoparticles decorated on MWCNTs as a novel electrode material for supercapacitor. Materials Science and Engineering: B,252, 114481.

Tatarchuk, T., Shyichuk, A., Trawczyńska, I., Yaremiy, I., Pędziwiatr, A. T., Kurzydło, P., Gargula, R. (2020). Spinel cobalt (II) ferrite-chromites as catalysts for H2O2 decomposition: Synthesis, morphology, cation distribution and antistructure model of active centers formation. Ceramics International, 46(17), 27517–27530.

Zaichuk, А. V., Amelina, А. А. (2018). Blue-green ceramic pigments in the system CaO–MgO–Al2O3–SiO2–СоО–Cr2O3 based on granulated blast-furnace slag. Voprosy khimii i khimicheskoi tekhnologii, (6), 120–124.

DOI: 10.32434/0321-4095-2018-121-6-120-124

Frolova, L., Pivovarov, A., Butyrina T. (2017). Synthesis of pigments in Fe2O3-Al2O3-CoO by co-precipitation method. Pigment & Resin Technology, 46(5), 356–361.

Frolova, L., Shuvalov, V. (2013). The technology of obtaining complex anticorrosive pigments from zinc-containing waste water. Chemistry & Chemical Technology, 7(2), 1–5.

Gao, H., Yang, H., Wang, S., Li, D., Wang, F., Fang, L., Yang, G. (2018). A new route for the preparation of CoAl2O4 nanoblue pigments with high uniformity and its optical properties. Journal of Sol-Gel Science and Technology, 86(1), 206–216.

Frolova, L., Pivovarov, A. (2016). Obtaining of brown pigments from concentrated waste water containing nickel. Chemistry and Chemical Technology, 10(2), 209–211.

Gonzalez, V., Wallez, G., Calligaro, T., Gourier, D., Menu, M. (2019). Synthesizing lead white pigments by lead corrosion: New insights into the ancient manufacturing processes. Corrosion Science, 146, 10–17.

Mindru, I., Gingasu, D., Patron, L., Ianculescu, A., Surdu, V. A., Culita, D. C., Oprea, O. (2019). A new approach: Synthesis of cobalt aluminate nanoparticles using tamarind fruit extract. Materials Science and Engineering: B, 246, 42–48.

Elakkiya, V., Sumathi, S. (2020). Low-temperature synthesis of environment-friendly cool yellow pigment: Ce substituted SrMoO4. Materials Letters, 263, 127246.

Gao, H., Wei, P., Liu, H., Long, M., Fu, H., & Qu, X. (2019). Sunlight-mediated lead and chromium release from commercial lead chromate pigments in aqueous phase. Environmental science & technology, 53(9), 4931–4939.

Monico, L., Sorace, L., Cotte, M., de Nolf, W., Janssens, K., Romani, A., &Miliani, C. (2019). Disclosing the Binding Medium Effects and the Pigment Solubility in the (Photo) reduction Process of Chrome Yellows (PbCrO4/PbCr1–xSxO4). ACS Omega, 4(4), 6607–6619.

Sangeetha, S., Basha, R., Sreeram, K. J., Sangilimuthu, S. N., & Nair, B. U. (2012). Functional pigments from chromium (III) oxide nanoparticles. Dyes and Pigments, 94(3), 548–552.

Chavarriaga-Miranda, E. A., Lopera-Sepúlveda, A. A., Montoya-Carvajal, J. F., Villada-Gil, S., &Restrepo-Baena, O. J. (2019). Green Inorganic Pigment Production with Spinel Structure CoCr2O4 by Solution Combustion Synthesis. Tecciencia, 14(26), 37–42.

Elias, Z., Poirot, O., Pezerat, H., H. Suquet, Schneider, O., Danière, M.C., Terzetti, F., Baruthio, F., Fournier, M., Cavelier, C. (1989). Cytotoxic and neoplastic transforming effects of industrial hexavalent chromium pigments in Syrian hamster embryo cells. Carcinogenesis, 10(11), 2043–2052.

Forsyth, J. E., Nurunnahar, S., Islam, S. S., Baker, M., Yeasmin, D., Islam, M. S., Luby, S. P. (2019). Turmeric means “yellow” in Bengali: Lead chromate pigments added to turmeric threaten public health across Bangladesh. Environmental research, 179, 108722.

Zhu, R., Ma, G., Cai, Y., Chen, Y., Yang, T., Duan, B., Xue, Z. (2016). Ceramic tiles with black pigment made from stainless steel plant dust: Physical properties and long-term leaching behavior of heavy metals. Journal of the Air & Waste Management Association, 66(4), 402–411.

Costa, G., Della, V. P., Ribeiro, M. J., Oliveira, A. P. N., Monrós, G., &Labrincha, J. A. (2008). Synthesis of black ceramic pigments from secondary raw materials. Dyes and Pigments, 77(1), 137–144.

de Sousa Santos, T. C., Almeida, A. C. M., do Rosario Pinheiro, D., Costa, C. M. L., Estumano, D. C., da Paixão Ribeiro, N. F. (2020). Synthesis and characterization of colourful aluminates based on nickel and zinc. Journal of Alloys and Compounds, 815, 152477.

Jose, S., Joshy, D., Narendranath, S. B., &Periyat, P. (2019). Recent advances in infrared reflective inorganic pigments. Solar Energy Materials and Solar Cells, 194, 7–27.

Frolova, L. A., Derhachov, M. P. (2017). The Effect of Contact Non-equilibrium Plasma on Structural and Magnetic Properties of MnХFe3−XО4 Spinels. Nanoscale research letters, 12(1), 505.

Sekine, I., Kato, T. (1986). Corrosion-protective properties of various ferrite paint films.Ind. Eng. Chem. Prod. Res. Dev., 25(1), 7–10.

Veselý, D., Neměc, P., Kalendova, A. (2011). Properties of ferrites with nonisometric shape of particles in organic coatings. Physica status solidi (c), 8(9), 2665–2668.

Mahvidi, S., Gharagozlou, M., Mahdavian, M., & Naghibi, S. (2017). Potency of ZnFe2O4 nanoparticles as corrosion inhibitor for stainless steel; the pigment extract study. Materials Research, 20(6), 1492–1502.


Ermilov, P.I., Indeykin E.A., Tolmachev I.A. (1987) [Pigmenty i pigmentirovannyie lakokrasochnyie materialyi]. L.: Himiya (in Russian).