VOLTAMMETRIC DETERMINATION OF VITAMIN B12 USING SOME AZO DYES

Authors

  • Svitlana V. Tymoshuk Ivan Franko National University of Lviv, Ukraine
  • Orest S. Fedyshyn Ivan Franko National University of Lviv, Ukraine
  • Lesya O. Kobryn Stepan Gzhytskyi National University of Veterinary Medicine and Biotechnologies of Lviv, Ukraine
  • Ihor O. Patsay Ivan Franko National University of Lviv, Ukraine
  • Lesya V. Oleksiv Ivan Franko National University of Lviv, Ukraine
  • Oleksandr S. Tymoshuk Ivan Franko National University of Lviv, Ukraine http://orcid.org/0000-0001-9812-4850

DOI:

https://doi.org/10.15421/jchemtech.v29i2.207847

Abstract

The article is devoted to the study of the voltammetric activity of Co(II) in the presense of azo dyes with further using of the results obtained in analytical practice. The voltammetric behaviour of Со(II) complexes with eriochrome red B, eriochrome black T, kalces and 1-[(5-(3-nitrobenzyl)-1,3-thiazol-2-yl)diazenyl]naphthalen-2-ol was investigated using cyclic linear sweep voltammetry. The optimal conditions for complex formation were established. New peaks caused by the reduction of the Co(II)–azodye complex compounds are observed on the voltammograms. Sensitive and highly reproducible methods for cobalt determination were developed using the linear dependence of peaks height on metal concentration with limit of detection of 10-7 mol·L-1. The accuracy of the proposed method was assessed by the method of standard additions. The developed method was successfully applied for the determination of vitamin B12 in pharmaceutical formulations.

 

Author Biography

Oleksandr S. Tymoshuk, Ivan Franko National University of Lviv

доцент кафедри аналітичної хімії

References

Vishnikin, A. B., Sidorova L. P., Voloboy A. O. (2019). Simultaneous spectrophotometric determination of food dyes in binary mixtures by H-point standard addition method. Journal of Chemistry and Technologies, 27(2), 276–284 https://doi.org/10.15421/081928

Chung, King-Thom (2016). Azo dyes and human health: A review. Journal of Environmental Science and Health, Part C Environmental Carcinogenesis and Ecotoxicology Reviews, 34(4), 233–261.

https://doi.org/10.1080/10590501.2016.1236602

Avci, G.A., Ozkinali, S., Ozluk, A., Avci, E., Kocaokutgen, H. (2012). Antimicrobial activities, absorption characteristics and tautomeric structures of o,o'-hydroxyazo dyes containing an acryloyloxy group and their chromium complexes. Hacettepe J. Biol. Chem., 40(2), 119–126.

Turan, N., Adiguzel, R., Buldurun, K., Bursal, E. (2016). Spectroscopic, thermal and antioxidant properties of novel mixed ligand-metal complexes obtained from saccharinate complexes and azodye ligand (mnppa). International Journal of Pharmacology, 12(2), 92–100. https://doi.org/10.3923/ijp.2016.92.100

Fizer, M., Sidey, V., Tupys, A., Ostapiuk, Y., Tymoshuk, O., Bazel, Y. (2017). On the structure of transition metals complexes with the new tridentate dye of thiazole series: Theoretical and experimental studies. Journal of Molecular Structure, 1149, 669–682. https://doi.org/10.1016/j.molstruc.2017.08.037

Pytlakowska, K., Kozik, V., Dabioch, M. (2013). Complex-forming organic ligands in cloud-point extraction of metal ions: a review. Talanta, 100, 202–228. http://dx.doi.org/10.1016/j.talanta.2013.02.037

Gaber, M., El-Ghamry, H.A., Fathalla, S.K. (2015). Ni(II), Pd(II) and Pt(II) complexes of (1H-1,2,4-triazole-3-ylimino)methyl]naphthalene-2-ol. Structural, spectroscopic, biological, cytotoxicity, antioxidant and DNA binding. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 139, 396–404. https://doi.org/10.1016/j.saa.2014.12.057

Niazi, A., Yazdanipour, A. (2008). Simultaneous spectrophotometric determination of cobalt, copper and nickel using 1-(2-thiazolylazo)-2-naphthol by chemometrics methods. Chinese Chem. Lett., 19, 860–864. https://doi.org/10.1016/j.cclet.2008.04.047

Gaber, M., Mansour, I. A., El-Sayed, Y. S. Y. (2007). Spectrophotometric, conductometric and thermal studies of Co(II), Ni(II) and Cu(II) complexes with 2-(2-hydroxynaphthylazo)-4-hydroxy-6-methyl-1,3-pyrimidine. Spectrochim. Acta A, 68, 305–311. https://doi.org/10.1016/j.saa.2006.11.035

Dinçalp, H., Toker, F., Durucasu, İ., Avcıbaşı, N., & Icli, S. (2007). New thiophene-based azo ligands containing azo methine group in the main chain for the determination of copper(II) ions. Dyes and Pigments, 75(1), 11–24.

https://doi.org/10.1016/j.dyepig.2006.05.015

Bazel, Y., Tupys, A., Ostapiuk, Y., Tymoshuk, O., Matiychuk, V. (2017). A green cloud-point microextraction method for spectrophotometric determination of Ni (II) ions with 1-[(5-benzyl-1,3-thiazol-2-yl)diazenyl]naphthalene-2-ol. Journal of Molecular Liquids, 242, 471–477.

https://doi.org/10.1016/j.molliq.2017.07.047

Tupys, A., Tymoshuk, O., Rydchuk, P. (2016). Spectrophotometric Investigation of Cu (II) Ions Interaction with 1-(5-Benzylthiazol-2-yl)azonaphthalen-2-ol. Chemistry & Chemical Technology, 10(1), 19–25.

https://doi.org/10.23939/chcht10.01.019

Bazel, Y., Tupys, A., Ostapiuk, Y., Tymoshuk, O., Imricha, J., Sandrejov, J. (2018). A simple non-extractive green method for the spectrophotometric sequential injection determination of copper(II) with novel thiazolylazo dyes. The Royal Society of Chemistry Advances, 8, 15940–15950.

https://doi.org/10.1039/c8ra02039f.

Terletskaya, A.V., Ievleva, O.S., Bogoslovskaya, T.A., Goncharuk, V.V. (2013). Selective Photometric Determination of Nickel, Cobal, and Zinc in Drinking and Natural Wat ers Using 1-(2-pyridylazo)-2-naphthol and Surfactants (SAS). J. Water Chem. Techno., 35(6), 246–252. https://doi.org/10.3103/S1063455X13060027

Tupys, A.M., Tymoshuk, O.S., Rydchuk, P.V. (2015). The Application of 1-(5-Benzylthiazol-2-yl)azonaphthalen-2-ol in Extraction-Photometric Analysis of the Main Soils Pollutants Content (Copper, Zinc, Cadmium and Lead). Methods and objects of chemical analysis, 10(2), 80–88. https://doi.org/10.17721/moca.2015.80-88

Chavan, S.S., Sawant, V.A. (2010). Synthesis, structural characterization, thermal and electrochemical studies of Mn(II), Co(II), Ni(II) and Cu(II) complexes containing thiazolylazo ligands. Journal of Molecular Structure, 965, 1–6. https://doi.org/10.1016/j.molstruc.2009.11.010

Shanthalakshmi, K., Belagali, S. L. (2009). Synthesis and spectrophotometric studies of some benzothiazolylazo dyes – determination of copper, zinc, cadmium, cobalt and nickel. Bulg. Chem. Commun., 41(4), 380–384.

Chavan, S.S., Yamgar, B.A., Bharate, B.G. (2013). Zn (II) and Cd(II)-azido/thiocyanato complexes with thiazolylazodye and triphenylphosphine: synthesis, characterization and fluorescence. J. Coord. Chem., 66(10), 1837–1846. http://dx.doi.org/10.1080/00958972.2013.791394

Tupys, A.M., Tymoshuk, O.S. (2015). Extraction-photometric determination of cadmium(II) using 1-(5-benzylthiazol-2-yl)azonaphthalen-2-ol. Bulletin of Dnipropetrovsk University, Series Chemistry, 23(1), 50–58. https://doi.org/10.15421/081507

Khan, S., Kazi, T.G., Soylak, M. (2014). Rapid ionic liquid-based ultrasound assisted dual magnetic microextraction to preconcentrate and separate cadmium-4-(2-thiazolylazo)-resorcinol complex from environmental and biological samples. Spectrochim. Acta A., 123, 194–199.

http://dx.doi.org/10.1016/j.saa.2013.12.065

Mahmoud, W.H., Omar, M.M., Sayed, F.N. (2016). Synthesis, spectral characterization, thermal, anticancer and antimicrobial studies of bidentate azodye metal complexes. Journal of Thermal Analysis and Calorimetry, 124(2), 1071–1089 https://doi.org/10.1007/s10973-015-5172-1

Tupys, A., Kalembkiewicz, J., Bazel, Y., Zapała, L., Dranka, M., Ostapiuk, Y., Tymoshuk, O., Woźnicka, E. (2017). 1-[(5-Benzyl-1,3-thiazol-2-yl)diazenyl]naph-thalene-2-ol: X-ray structure, spectroscopic characterization, dissociation studies and application in mercury(II) detection. J. Mol. Struct., 1127, 722–733. http://dx.doi.org/10.1016/j.molstruc.2016.07.119

Tupys, A., Tymoshuk, O. (2015). 1-(5-Benzylthiazol-2-yl)azonaphthalen-2-ol — a new reagent for the determination of Pd(II). Acta Chimica Slovaca, 8(1), 59–64. https://doi.org/10.1515/acs-2015-0011

Fedyshyn, O., Bazel, Y., Fizer, M., Sidey, V., Imrich, J., Vilkova, M., Barabash, O., Ostapiuk, Y., Tymoshuk, O. (2020). Spectroscopic and computational study of a new thiazolylazonaphthol dye1-[(5-(3-nitrobenzyl)-1,3-thiazol-2-yl)diazenyl]naphthalen-2-ol. J. Mol. Liquids, 304, 112713.

https://doi.org/10.1016/j.molliq.2020.112713

Tymoshuk, O. S., Fedyshyn, O. S., Oleksiv, L. V., Rydchuk, P. V., Patsai, I. O. (2019). A new method of control over the content of palladium in intermetallic alloys. Materials Science, 55, 455–459.

https://doi.org/10.1007/s11003-019-00325-9

Levitskaya, G. D., Timoshuk, S. V., Gritsai, V. M. (2003). [Oscillopolarography of palladium(II)-Tropeolin 0 complexes]. Journal of Analytical Chemistry, 58 (11), 1065-1068. https://doi.org/10.1023/A:10273853 06485 (in Russian).

Naser, N.A., Kahdim, K.H., Taha, D.N. (2012). Synthesis and Characterization of an Organic Reagent 4-(6-Bromo-2-Benzothiazolylazo) Pyrogallol and Its Analytical Application. J. Oleo Sci., 61, 387–392. https://doi.org/10.5650/jos.61387

Mohammed, H.J., Syhood, A.A. (2018). Spectrophotometric, thermal and determination of trace amount of palladium (II) nickel (II) and silver (I) by using pyrazolone azo derivative. J Anal Pharm Res., 7(4), 504‒511.

https://doi.org/10.15406/japlr.2018.07.00275

Rydchuk, M., Mykhalyna, G., Dobryanska, O., Korkuna, O., Vrublevska, T. (2011). Osmium assay in fixatives and stained rat tissues by means of acid and o,o′-dihydroxo substituted monoazo dyes and some flavonoids. Cent. Eur. J. Chem., 9(5), 886–895. https://doi.org/10.2478/s11532-011-0070-2

Shiri, S, Delpisheh, A, Haeri, A, Poornajaf, A, Khezeli, T, Badkiu, N. (2011). Floatation-spectrophotometric Determination of Thorium, Using Complex Formation with Eriochrome Cyanine R. Anal Chem Insights., 6, 1–6. https://doi.org/10.4137/ACI.S5949

Tvorynska, S., Josypčuk, B., Barek, J., Dubenska, L. (2019). Electrochemical behavior and sensitive methods of the voltammetric determination of food azo dyes amaranth and Allura Red AC on amalgam electrodes. Food Anal. Methods, 12, 409–421. https://doi.org/10.1007/s12161-018-1372-1

Al-Adilee, K.J., Abass, A.K., Taher, A.M. (2016). Synthesis of some transition metal complexes with new heterocyclic thiazolyl azodye and their uses as sensitizers in photo reactions. J. Mol. Struct., 1108, 378–397. https://doi.org/10.1016/j.molstruc.2015.11.038

Al-Sheikh, M., Medrasi, H. Y., Sadek, K. U., Mekheimer, R. A. (2014). Synthesis and Spectroscopic Properties of new azo dyes derived from 3-ethylthio-5-cyanomethyl-4-phenyl-1,2,4-triazole. Molecules, 19, 2993–3003 https://doi.org/10.3390/molecules19032993

Tupys, A.M. [Spektrofotometriya spoluk 1-(5-benzyl-2-il)azonaftalen-2-olu z ionamy perekhidnykh metaliv ta yikh zactosuvannya v analizi], Ushgorod, 2017. (in Ukrainen).

Herbert, V. (1988). Vitamin B-12: plant sources, requirements, and assay. The American Journal of Clinical Nutrition, 48(3), 852–858. https://doi.org/10.1093/ajcn/48.3.852

Karmi, O., Zayed, A., Baraghethi, S., Qadi, M., Ghanem, R. (2011). Measurement of Vitamin B12 concentration. A Review on available methods. The IIOAB Journal, 2(2), 23–32.

Firoj, Ahmed, Banoo, Rebecca, Ghazi, Muhammed Sayedur, Rahman, Md. Omar Fakur Khan (2003). A convenient colorimetric assay method for determination of vitamin B12 content in pharmaceutical preparation. J. Med. Sci, 3(2), 163–168. https://doi.org/10.3923/jms.2003.163.168

Adolfo, F. R., do Nascimento, P. C., Bohrer, D., de Carvalho, L. M., Viana, C., Guarda, A., Mattiazzi, P. (2016). Simultaneous determination of cobalt and nickel in vitamin B12 samples using high-resolution continuum source atomic absorption spectrometry. Talanta, 147, 241–245. https://doi.org/10.1016/j.talanta.2015.09.073

Tsiminis, G., Schartner, E. P., Brooks, J. L., Hutchinson, M. R. (2017). Measuring and tracking vitamin B12: A review of current methods with a focus on optical spectroscopy. Applied spectroscopy reviews, 52(5), 439–455. https://doi.org/10.1080/05704928.2016.1229325

Şükrü, K., Ülkü, Ü., Güler, S. (2020). Determination of Vitamin B12 Using Differential Pulse Polarography. American Journal of Analytical Chemistry, 11(5), 187–196.

https://doi.org/10.4236/ajac.2020.115014

Dubenskaya, L. O., Levitskaya, G. D., Poperechnaya, N. P., Tymoshuk, S. V., & Kopot’, O. V. (2005). Voltammetric Reduction of In(III)-Eriochrome Red B Complexes. Journal of Analytical Chemistry, 60(11), 1052–1055. https://doi.org/10.1007/s10809-005-0237-0

Downloads

Published

2021-07-20