SOLVENT SELECTION FOR EXTRACTION OF TARGET COMPONENTS FROM AMBER
Keywords:екстрагування, бурштин, сукциніт, розчинник, скам’яніла смола
Amber (succinite) is a potential source of a natural biologically active components complex that are promising to use for its intended purpose in various industries. In the presented work a wide range of multipolar solvents for extraction of target components from amber of Volyn region (Ukraine) is investigated, their influence on efficiency of this process and qualitative characteristics of the received extract is noted. For a number of organic solvents, the extraction efficiency of soluble solids as a quantitative characteristic of the solvent was studied. According to this indicator, the best extractants are white spirit, ethanol, acetone and petroleum ether. As an indicator of the quantitative efficiency of extraction of dyes represented in the raw material by the fraction of the resin, it is possible to use the optical density value of the extracts, with the highest values obtained in the case of acetone and ethanol. The redox potential value of the obtained extracts increases in the extraction process with all solvents except water, with which this indicator did not change. The change in color and structure of the obtained meal is illustrated by photographs of the appearance of amber after extraction. Low polar solvents, such as acetone and ethanol, which can remove both hydrophilic and hydrophobic substances, have been found to be most effective for extraction of target components from amber. In industries that work with technologies and products with high safety requirements, it is advisable to use ethanol to extract the target components from amber
Rezaei, M., Ghasemi Pirbalouti, A. (2019). Phytochemical, antioxidant and antibacterial properties of extracts from two spice herbs under different extraction solvents. Food Measurement and Characterization, 13, 2470–2480.
Brás, T., Neves, L. A., Crespo, J.G., Duarte, M. F. (2020). Effect of extraction methodologies and solvent selection upon cynaropicrin extraction from Cynara cardunculus leaves. Separation and Purification Technology, 236, 116283.
Pintac, D., Majkic, T., Torovic, L., Orcic, D., Beara, I., Simin, N., Mimica-Dukic, N., Lesjak, M. (2018). Solvent selection for efficient extraction of bioactive compounds from grape pomace. Industrial Crops and Products, 111, 379–390.
Efthymiopoulos, I., Hellier, P., Ladommatos, N., Russo-Profili, A., Eveleigh, A., Aliev, A., Kay, A., Mills-Lamptey, B. (2018). Influence of solvent selection and extraction temperature on yield and composition of lipids extracted from spent coffee grounds. Industrial Crops and Products, 119, 49-56.
Malashenkov, B. M. (2018). Amber industry of the Russian Federation and the world amber market. Gosudarstvennoye upravleniye: Elektronnyy vestnik, 69, 103-126 (in Russian).
Langenheim, J. (2003). Plant Resins: Chemistry, Evolution, Ecology, and Ethnobotany. Portland, Cambridge: Timber Press Inc.
Synoradzki, L., Arct, J., Safarzyński, S., Hajmowicz, H., Sobiecka, A., Dankowska, E. (2012). Characteristics and application of Baltic amber in pharmaceutical and cosmetic industries. Przemysl Chemiczny, 91(1), 89–94.
Mikučionienė, D., Milašius, R., Daugelavičius, R., Ragelienė, L., Venslauskaitė, N., Ragaišienė, A., Rukuižienė, Ž. (2016) Preliminary investigation into the antimicrobial activity of an electrospun polyamide nanofibrous web with micro particles of Baltic amber. Fibres and Textiles in Eastern Europe, 24(5), 34–37. https://doi.org/10.5604/12303666.1215524
Savkevich, S.S. (1970). [Yantar]. Leningrad, USSA: Nedra (in Russian).
Simkha, G.V., (2016). Ukraine Patent No. 108098. Kyiv, Ukraine. Ukrainian Institute of Industrial Property.
Mironov, O.L., Kachalova, N.M., Dzyuba, O.I., Bogza, S.L. (2017). Complex of biologically active amber compounds: method of production, properties and application // Modern aspects of human health: proceeds of X International. interdiscipline. sci.-pract. conf. 247–251 (in Ukrainian).
Fedoseeva, E. (2017). Is there honey from amber?. Argumenty i fakty, 81 (in Russian).
Srebrodolsky, B.I. (1980). [Amber of Ukraine]. Kyiv, USSR: Naukova dumka (in Russian).
Blazheevskiy, M., Koretnik, O. (2013). Oxidation-reduction potential of peroxomonosulphate/sulphate system and its dependence on рH medium. Proc. Shevchenko Sci. Soc. Chem. Biochem, 33, 28–34 (in Ukrainian).
Huang, P., Wen, G., Shang, Z., Zhang, C., Lin, Z., Zhang, J. (2017). Spectral correlation analysis of chlorophyll-a concentration for inland water. 10th International Congress on Image and Signal Processing, BioMedical Engineering and Informatics (CISP-BMEI), 1–5. https://doi.org/10.1109/CISP-BMEI.2017.8302033
Rao, B., and Tang, R-Ch. (2017). Green synthesis of silver nanoparticles with antibacterial activities using aqueous Eriobotrya japonica leaf extract. Advances in Natural Sciences: Nanoscience and Nanotechnology, 8(1), 015014.
Koldaev, V. M., Manyakhin, A. Y. (2018). Numerical indicators of absorption spectra of green leaf extract obtained from plants of different life forms. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 203, 404–407.
Makarova, E.Y., Maslova, E.E., Marek, J. (2017). Investigation of fossil resins and amber. Georesursy,19, 249-255. http://doi.org/10.18599/grs.19.24
Tumiłowicz, P., Synoradzki, L., Sobiecka, A., Arct, J., Pytkowska, K., Safarzyński, S. (2016). Bioactivity of Baltic amber – fossil resin. Polimery, 5, 347–356. http://dx.doi.org/10.14314/polimery.2016.347
Angeloni, G., Guerrini, L., Masella, P., Bellumori, M., Daluiso, S., Parenti, A., Innocenti, M. (2019). What kind of coffee do you drink? An investigation on effects of eight different extraction methods. Food Research International, 116, 1327–1335.
Stanojevic, L.P., Stankovic, M.Z., Cvetkovic, D.J., Cakic, M.D., Ilic, D.P., Nikolic, V.D., Stanojevic, J.S. (2016). The effect of extraction techniques on yield, extraction kinetics, and antioxidant activity of aqueous-methanolic extracts from nettle (Urtica dioica L.) leaves. Separation Science and Technology, 51(11), 1817–1829. https://doi.org/10.1080/01496395.2016.1178774
Yang, Z., Du, M., Jiang, J. (2016). Reducing capacities and redox potentials of humic substances extracted from sewage sludge. Chemosphere, 144, 902–908. https://doi.org/10.1016/j.chemosphere.2015.09.03
Copyright (c) 2021 Дніпровський національний університет імені Олеся Гончара
This work is licensed under a Creative Commons Attribution 4.0 International License.
- Authors reserve the right of attribution for the submitted manuscript, while transferring to the Journal the right to publish the article under the Creative Commons Attribution License. This license allows free distribution of the published work under the condition of proper attribution of the original authors and the initial publication source (i.e. the Journal)
- Authors have the right to enter into separate agreements for additional non-exclusive distribution of the work in the form it was published in the Journal (such as publishing the article on the institutional website or as a part of a monograph), provided the original publication in this Journal is properly referenced
- The Journal allows and encourages online publication of the manuscripts (such as on personal web pages), even when such a manuscript is still under editorial consideration, since it allows for a productive scientific discussion and better citation dynamics (see The Effect of Open Access).