UV-CURABLE PROTON CONDUCTIVE ORGANIC-INORGANIC MEMBRANES BASED ON ACRYLIC MONOMERS AND SOL-GEL DERIVED SILICA

Authors

  • Iryna Yu. Yevchuk L.M. Lytvynenko Institute of Physico-organic Chemistry and Coal Chemistry NAS of Ukraine
  • Mariia М. Zhyhailo Віділення фізико-хімії горючих копалин Інституту фізико-органічної хімії та вуглехімії ім. Л.М. Литвиненка НАН України

DOI:

https://doi.org/10.15421/082109

Abstract

This article describes the synthesis and characterization of the new UV-curable cross-linked hybrid polymer-inorganic materials. The membranes were synthesized via UV-initiated copolymerization in situ based both on hydrophilic and hydrophobic acrylic monomers with the simultaneous formation of inorganic network in sol-gel reaction of precursors 3-methacryloxypropyl trimethoxysilane (MAPTMS) and tetraethyl orthosilicate (TEOS). The composition of the polymeric counterpart was varied by changing the ratio of hydrophilic and hydrophobic monomers while the content of the inorganic counterpart was kept constant. FTIR, SEM were used to characterize the morphology and chemical structure of the resulting membranes. The proton conductivity, oxidative stability, water and methanol uptake of the synthesized membranes were measured, and strong correlation between the properties of the membranes and the monomer ratio (AMPS : AA) was established, which makes it possible to regulate the membrane characteristics. The obtained new UV-curable cross-linked hybrid polymer-inorganic materials can be used for the development of the proton-conducting membranes for fuel cells.

Author Biography

Mariia М. Zhyhailo, Віділення фізико-хімії горючих копалин Інституту фізико-органічної хімії та вуглехімії ім. Л.М. Литвиненка НАН України

Відділ хімії окислювальних процесів, аспірант.

References

References

Wang Y., Ruiz Diaz D., Chen K., Wang Z., Adroher X. (2020). Materials, technological status, and fundamentals of PEM fuel cells – A review. Materials Today. 32, 178-203. doi.org/10.1016/j.mattod.2019.06.005

Daud W., Rosli R., Majlan E., Hamid S., Mohamed R. (2017). PEM fuel cell system control: A review. Renewable Energy. 113, 620-638. doi.org/10.1016/j.renene.2017.06.027

Gielen D., Boshell F., Saygin D., Bazilian M., Wagner N., Gorini R. (2019). The role of renewable energy in the global energy transformation. Energy Strategy Reviews. 24, 38-50. doi.org/10.1016/j.esr.2019.01.006

Pal S., Mondal R., Guha S., Chatterjee U., Jewrajka S. (2019). Homogeneous phase crosslinked poly(acrylonitrile-co-2-acrylamido-2-methyl-1-propanesulfonic acid) conetwork cation exchange membranes showing high electrochemical properties and electrodialysis performance. Polymer. 180, 121680. doi.org/10.1016/j.polymer.2019.121680

Ye Y-S, Rick J., Hwang B-J. (2012). Water Soluble Polymers as Proton Exchange Membranes for Fuel Cells. Polymers. 4, 913-963. doi:10.3390/polym4020913

Erkartal M., Aslan A., Erkilic U., Dadi S., Yazaydin O., Usta H., Sen U. (2016). Anhydrous proton conducting poly(vinyl alcohol) (PVA) / poly(2-acrylamido-2-methylpropane sulfonic acid (PAMPS)/1,2,4-triazole composite membrane. International Journal of Hydrogen Energy. 41, 11321-11330. doi.org/10.1016/j.ijhydene.2016.04.152

Nesic A., Panic V., Ostojic S., Micic D., Pajic-Lijakovic I., Onjia A., Velickovic S. (2016). Physical-chemical behavior of novel copolymers composed of methacrylic acid and 2-acrylamido-2-methylpropane sulfonic acid. Materials Chemistry and Physics. 174, 156-163. doi.org/10.1016/j.matchemphys.2016.02.063

Jiang Z., Zheng X., Wu H., Wang J., Wang Y. (2008). Proton conducting CS/P(AA-AMPS) membrane with reduced methanol permeability for DMFCs Chemistry. Journal of Power Sources. 180, 143–153. doi.org/10.1016/j.jpowsour.2008.01.049

Karlsson L., Wesslén B., Jannasch P. (2002). Water absorption and proton conductivity of sulfonated acrylamide copolymers. Electrochimica Acta. 47, 3269-3275. doi: 10.1016/S0013-4686(02)00244-X

Randin J.-P. (1982). Ion-containing polymers as semisolid electrolytes in WO3-based electrochromic devices. J. Electrochem. Soc. 129, 1215-1220.

Karlsson L., Jannasch P., Wesslén B. (2002). Preparation and solution properties of amphiphilic sulfonated acrylamide copolymers. Macromolecular Chemistry and Physics. 203, 686-694. doi: 10.1002/1521-3935(20020301)203:4<686::AID-MACP686>3.0.CO;2-C

Shen Y., Xi J., Qiu X., Zhu W. (2007). A new proton conducting membrane based on copolymer of methyl methacrylate and 2-acrylamido-2-methyl-1-propanesulfonic acid for direct methanol fuel cells. Electrochimica Acta. 52, 6956-6961. doi: 10.1016/j.electacta.2007.05.021

Qiao J., Hamaya T., Okada T. (2005). Chemically modified poly(vinyl alcohol)−poly(2-acrylamido-2-methyl-1-propanesulfonic acid) as a novel proton-conducting fuel cell membrane. Chem. Mater. 17, 2413-2421. doi.org/10.1021/cm048260t

Qiao J., Hamaya T., Okada T. (2005). New highly proton-conducting membrane poly(vinyl pyrrolidone) (PVP) modified poly(vinyl alcohol)/2-acrylamido-2-methyl-1-propanesulfonic acid (PVA-PAMPS) for low temperature direct methanol fuel cells (DMFCs). Polymer. 46, 10809-10816. doi.10.1016/j.polymer.2005.09.007

Hamaya T., Inoue S., Qiao J., Okada T. (2006). Novel proton-conducting polymer electrolyte membranes based on PVA/PAMPS/PEG400 blend. Journal of Power Sources. 156, 311-314. doi: 10.1016/j.jpowsour.2005.07.002

Kamjornsupamitr T., Sangthumchai T., Saejueng P., Sumranjit J., Hunt A., Budsombat S. (2020). Composite proton conducting membranes from chitosan, poly(vinyl alcohol) and sulfonic acid-functionalized silica nanoparticles. International Journal of Hydrogen Energy. Available online 5 November. doi: 10.1016/j.ijhydene.2020.10.062

Hench L., West J. (1990). The Sol-Gel Process. Chemical Reviews. 90, 1, 33-72. doi.org/10.1021/cr00099a003

Pierre A. (1998). Introduction to sol-gel processing. Springer Book Archive. doi.org/10.1007/978-1-4615-5659-6

Huang S., Chin W., Yang W. (2005). Structural characteristics and properties of silica/poly(2-hydroxyethyl methacrylate) (PHEMA) nanocomposites prepared by mixing colloidal silica or tetraethyloxysilane (TEOS) with PHEMA. Polymer. 46, 1865–1877. doi.org/10.1016/j.polymer.2004.12.052

Sanchez C., Lebeau B., Ribot F., In M. (2000). Molecular Design of Sol-Gel Derived Hybrid Organic-Inorganic Nanocomposites. Journal of Sol-Gel Science and Technology. 19, 31–38. doi.org/10.1023/A:1008753919925

Zhyhailo M., Demchyna O., Demydova Kh., Yevchuk I. (2018). Investigation of viscosity of sol-gel systems based on 3-methacryloxy-propyltrimethoxysilane and tetraethoxysilane. Series of Chemistry, Materials Technology and their Application. 886, 58-67.

Zhyhailo M., Yevchuk I., Yatsyshyn M., Korniy S., Demchyna O., Musiy R., Raudonis R., Zarkov A., Kareiva A. (2020). Preparation of polyacrylate/silica membranes for fuel cell application by in situ UV polymerization. Chemija. 31, 247-254. doi.org/10.6001/chemija.v31i4.4321

Abdraboh A., Abdel-Aal A., Ereiba K. (2020). Preparation and Characterization of Inorganic Organic Hybrid Material Based on TEOS/MAPTMS for Biomedical Applications. Silicon. doi.org/10.1007/s12633-020-00460-y

Criado M., Sobrados I., Sanz J. (2014). Polymerization of hybrid organic–inorganic materials from several silicon compounds followed by TGA/DTA, FTIR and NMR techniques. Progress in Organic Coatings. 77, 880-891. doi.org/10.1016/j.porgcoat.2014.01.019

Abu-Saied M., Soliman E., Desouki E. (2020). Development of Proton Exchange Membranes Based on Chitosan Blended with Poly (2-Acrylamido-2-Methylpropane Sulfonic Acid) for Fuel Cells applications. Materials Today Communications. 25, 101536. doi.org/10.1016/j.mtcomm.2020.101536

Zhyhailo M., Demchyna O., Demydova Kh., Yevchuk I., Rachiy B. (2019).Proton Conductive Organic-Inorganic Nanocomposite Membranes Derived by Sol-Gel Method. Chemistry & Chemical Technology. 13, 436-443. doi.org/10.23939/chcht13.04.436

Zhyhailo M., Demchyna O., Yevchuk I., Rachiy B., Kochubey V. (2019). Preparation and characterization of UV-curable cross-linked organic-inorganic membranes. Issues of Chemistry and Chemical Technology. 5, 34-41. DOI:10.32434/0321-4095-2019-126-5-34-41

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Published

2021-04-26