EVALUATION OF THE CONTRIBUTION OF ION EXCHANGE IN THE PROCESS OF DEMANGANIZATION WITH MODIFIED CATION EXCHANGE RESIN KU-2-8
DOI:
https://doi.org/10.15421/jchemtech.v29i4.242561Keywords:
demanganization, ion exchange, catalytic oxidation, artesian water, magnetiteAbstract
An effective method of water purification from manganese compounds is the use of magnetite, so it is advisable to improve the way it is used. The main disadvantage of using dispersed microcrystalline magnetite is the difficulty of implementing water purification in dynamic conditions, due to the significant resistance to water filtration. In the case of the use of magnetite in static conditions, there is a constant consumption of magnetite after settling and filtration, and the demanganization process requires the use of bulky and poorly mobile installations (mixers, settling tanks and filters). Therefore, water purification from manganese ions was carried out under dynamic conditions by filtering water through a layer of strong acid cation exchange resin KU-2-8 in H+, Na+, Ca2+ forms modified with magnetite. This allows constant contact of the solution with the ion exchange material and reduces the role of the limiting diffusion factor on the water purification process. When evaluating the effectiveness of cation exchange resin KU-2-8 in the extraction of Mn2+ ions from water depending on the form of the resin, it was found that the FEDC for the resin in H+ form is 2198 mg-eq/dm3, for Na+ it is 2175 mg-eq/dm3 and for Ca2+ the value is 1717 mg-eq/dm3. Therefore, during the transition from H+ to Na+ and to Ca2+ form there is a decrease in the sorption capacity for Mn2+ ions in the cation exchange resin KU-2-8. On the cation exchange resin in Ca2+ form the efficiency of demanganization decreases with increasing concentration of manganese ions. When increasing the initial concentration from 5 to 10 and 30 mg/dm3 in distilled water, the residual concentration increases from 0.14 to 0.35 and up to 1.95 mg/dm3 when filtered through 10 cm3 of resin in Ca2+ form. When removing Mn2+ ions from artesian water, the residual concentration was 4.0; 7.0 and 27.0 mg/dm3 respectively. Thus, on magnetite-modified cation exchange resin, manganese ions are removed only partially due to ion exchange and their complete removal from water is possible only due to catalytic oxidation and deposition on magnetite.
References
Remeshevska, I., Trokhymenko, G., Gurets, N., Stepova, O., Trus, I., & Akhmedova, V. (2021). Study of the ways and methods of searching water leaks in water supply networks of the settlements of Ukraine. Ecological Engineering and Environmental Technology, 22(4), 14–21. https://doi.org/10.12912/27197050/137874
Marsidi, N., Abu Hasan, H., & Sheikh Abdullah, S. R. (2018). A review of biological aerated filters for iron and manganese ions removal in water treatment. Journal of Water Process Engineering, 23, 1–12. https://doi.org/10.1016/j.jwpe.2018.01.010
Novita, E., Pradana, H. A., Purnomo, B. H., & Puspitasari, A. I. (2020). River water quality assessment in east java, Indonesia. Journal of Water and Land Development, 47(1), 135–141.
https://doi.org/10.24425/jwld.2020.135040
Trus, I., Gomelya M. (2021). Desalination of mineralized waters using reagent methods. Journal of Chemistry and Technologies, 29(3), 417–424. https://doi.org/10.15421/jchemtech.v29i3.214939
Trus, I., Gomelya, N., Halysh, V., Radovenchyk, I., Stepova, O., & Levytska, O. (2020). Technology of the comprehensive desalination of wastewater from mines. Eastern-European Journal of Enterprise Technologies, 3(6-105), 21–27.
https://doi.org/10.15587/1729-4061.2020.206443
Podgórni, E., & Rząsa, M. (2014). Investigation of the effects of salinity and temperature on the removal of iron from water by aeration, filtration, and coagulation. Polish Journal of Environmental Studies, 23(6), 2157–2161. DOI: https://doi.org/10.15244/pjoes/24927
Trus, I., Halysh, V., Gomelya, M., & Radovenchyk, V. (2021). Low-waste technology for water purification from iron ion. Ecological Engineering and Environmental Technology, 22(4), 116–123. DOI: https://doi.org/10.12912/27197050/137860
Trus, I., Halysh, V., Radovenchyk, Y., & Fleisher, H. (2020). Conditioning of iron-containing solutions. Journal of Chemical Technology and Metallurgy, 55(2), 486–491.
Kassim A.A., Abdullah, N., Yahya, M.Z. (2019). The pre-evaluation of crosslinked anion exchange (CAX) resin on nitrates removal. Journal of Chemical Engineering and Industrial Biotechnology, 5(2), 1–8. https://doi.org/10.15282/jceib.v5i2.3762
Sun Y., Zheng W., Ding X., Singh R. P. (2020). Selective removal of nitrate using a novel asymmetric amine based strongly basic anion exchange resin. Adsorption Science and Technology, 38(5), 026361742094583 http://dx.doi.org/10.1177/0263617420945839
Cheng, L. -., Xiong, Z. -., Cai, S., Li, D. -., & Xu, X. -. (2020). Aeration-manganese sand filter-ultrafiltration to remove iron and manganese from water: Oxidation effect and fouling behavior of manganese sand coated film. Journal of Water Process Engineering, 38. https://doi.org/10.1016/j.jwpe.2020.101621
Tobiason, J.E., Brazilio, A., Goodwill, J., Mai, X., Nguyen, C. (2016). Manganese removal from drinking water sources. Current Pollution Reports, 2, 168–177. https://doi.org/10.1007/s40726-016-0036-2
Alijani Galangashi, M., Masoumi Kojidi, S. F., Pendashteh, A., Abbasi Souraki, B., & Mirroshandel, A. A. (2021). Removing iron, manganese and ammonium ions from water using greensand in fluidized bed process. Journal of Water Process Engineering, 39. https://doi.org/10.1016/j.jwpe.2020.101714
Prodanović, J. M., & Vasić, V. M. (2013). Application of membrane processes for distillery wastewater purification-a review. Desalination and Water Treatment, 51(16-18), 3325-3334. https://doi.org/10.1080/19443994.2012.749178
Kononova, O. N., Bryuzgina, G. L., Apchitaeva, O. V., & Kononov, Y. S. (2019). Ion exchange recovery of chromium (VI) and manganese (II) from aqueous solutions. Arabian Journal of Chemistry, 12(8), 2713-2720. https://doi.org/10.1016/j.arabjc.2015.05.021
O’Neal, S. L., & Zheng, W. (2015). Manganese toxicity upon overexposure: A decade in review. Current Environmental Health Reports, 2(3), 315–328. http://dx.doi.org/10.1007/s40572-015-0056-x
Flem, B., Reimann, C., Fabian, K., Birke, M., Filzmoser, P., & Banks, D. (2018). Graphical statistics to explore the natural and anthropogenic processes influencing the inorganic quality of drinking water, ground water and surface water. Applied Geochemistry, 88, 133-148. https://doi.org/10.1016/j.apgeochem.2017.09.006
De Meyer, C.M.C., Rodríguez, J.M., Carpio, E.A., García, P.A., Stengel, C., Berg, M. (2017). Arsenic, manganese and aluminum contamination in groundwater resources of Western Amazonia (Peru). Sci. Total Environ., 607-608, 1437–1450.
https://doi.org/10.1016/j.scitotenv.2017.07.059
Vega, M.A., Kulkarni, H.V., Mladenov, N., Johannesson, K., Hettiarachchi, G.M., Bhattacharya, P., Kumar, N., Weeks, J., Galkaduwa, M., Datta, S. (2017). Biogeochemical controls on the release and accumulation of Mn and As in shallow aquifers, West Benal, India. Front. Environ. Sci., 5, 29. https://doi.org/10.3389/fenvs.2017.00029
Biela, R., & Kučera, T. (2016). Efficacy of sorption materials for nickel, iron and manganese removal from water. Procedia Engineering, 162, 56-63. https://doi.org/10.1016/j.proeng.2016.11.012
Flieger, J., Kawka, J., Płaziński, W., Panek, R., & Madej, J. (2020). Sorption of heavy metal ions of chromium, manganese, selenium, nickel, cobalt, iron from aqueous acidic solutions in batch and dynamic conditions on natural and synthetic aluminosilicate sorbents. Materials, 13(22), 1-18. https://doi.org/10.3390/ma13225271
Vistuba, J. P., Nagel-Hassemer, M. E., Lapolli, F. R., & Recio, M. A. L. (2013). Simultaneous adsorption of iron and manganese from aqueous solutions employing an adsorbent coal. Environmental Technology (United Kingdom), 34(2), 275–282. https://doi.org/10.1080/09593330.2012.692716
Ormanci, T., Demirkol, G.T., Aydın, I.M., Tufekci, N. (2013). An experimental study on manganese(II) removal with manganese dioxide recycling. Desalination and Water Treatment, 51(10–12), 2225–2230. http://dx.doi.org/10.1080/19443994.2012.734731
Massoudinejad, M., Khashij, M. (2014). Absorption isotherm study of Mn2+ on MnO2 and FeO – coated zeolite from aqueous solution. International Journal of Advanced Science and Technology, 72, 63–72.http://dx.doi.org/10.14257/ijast.2014.72.06
Patent 93087 Ukraine: МPК B01J 20/02, CO2F 1/64. The method of obtaining a load for water purification from manganese compounds: Publ. 25.09.2014, Bulletin № 14.
Mamchenko, A. V., & Chernova, N. N. (2013). Water purification of manganes compounds by a sorbent-catalyst at diferent pH and salt content. Journal of Water Chemistry and Technology, 35(1), 30–35. http://dx.doi.org/10.3103/S1063455X13010050
Gogoi, D., Shanmugamani, A. G., Rao, S. V. S., Kumar, T., & Velmurugan, S. (2016). Study of removal process of manganese using synthetic calcium hydroxyapatite from an aqueous solution. Desalination and Water Treatment, 57(14), 6566––6573.
http://dx.doi.org/10.1080/19443994.2015.1010588
Cerrato, J. M., Knocke, W. R., Hochella Jr., M. F., Dietrich, A. M., Jones, A., & Cromer, T. F. (2011). Application of XPS and solution chemistry analyses to investigate soluble manganese removal by MnO x(s)-coated media. Environmental Science and Technology, 45(23), 10068–10074. https://doi.org/10.1021/es203262n
Ferrier, J., Yang, Y., Csetenyi L., Michael G. G. (2019). Colonization, Penetration and Transformation of Manganese Oxide Nodules by Aspergillus niger. Environmental Microbiology, 21(5). http://dx.doi.org/10.1111/1462-2920.14591
Maghrabi, A.H. El, Marzouk, M.A., Elbably, M.A., Hassouna, M.E.M. (2020). Biosorption of Manganese by Amended Aspergillus versicolor from Polluted Water Sources. Nature Environment and Pollution Technology, 19 (4), 1645–1656.
https://doi.org/10.46488/NEPT.2020.v19i04.032
Fadel, M., Hassanein, N.M., Elshafei, M.M., Mostafa, A.H., Ahmed, M.A., Khater, H.M. (2017). Biosorption of manganese from groundwater by biomass of Saccharomyces cerevisiae. HBRC J.,13 (1), 106–113. http://dx.doi.org/10.1016/j.hbrcj.2014.12.006
Diaz-Alarcón, J. A., Alfonso-Pérez, M. P., Vergara-Gómez, I., Díaz-Lagos, M., & Martínez-Ovalle, S. A. (2019). Removal of iron and manganese in groundwater through magnetotactic bacteria. Journal of Environmental Management, 249, 109381. https://doi.org/10.1016/j.jenvman.2019.109381
Trus, I., Gomelya, N., Trokhymenko, G., Magas, N., & Hlushko, O. (2019). Determining the influence of the medium reaction and the technique of magnetite modification on the effectiveness of heavy metals sorption. Eastern-European Journal of Enterprise Technologies, 6(10-102), 49–54.
https://doi.org/10.15587/1729-4061.2019.188295
Trus, I., Gomelya, M., Chuprinov, E., Pylypenko, T. (2021). Optimization of dose calculation of modified magnetite during sorption purification of water from copper ions to create environmentally friendly technology // E3S Web of Conferences, 280, 10001. https://doi.org/10.1051/e3sconf/202128010001
Gomelya, M., Tverdokhlib, M., Shabliy, T., & Linyucheva, O. (2021). Usage of sorbent-catalyst to accelerate the oxidation of manganese. Journal of Ecological Engineering, 22(4), 232–239.
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