CHARACTERISTICS OF THE COMPOSITE POLYMERIC MATERIAL DIATOMIC-ALGINATE -Fe3O4

Authors

  • Liliya A. Frolova Ukrainian State University of Chemical Technology, Ukraine https://orcid.org/0000-0001-7970-2264
  • Oleksandr O. Pasenko Ukrainian State University of Chemical Technology, Ukraine
  • Konstantin M. Sukhyy Ukrainian State University of Chemical Technology, Ukraine

DOI:

https://doi.org/10.15421/jchemtech.v30i2.243768

Keywords:

diatomite; magnetite; magnetic nanoparticle, adsorption;

Abstract

The use of composite polymeric adsorbents containing components of natural origin, environmentally friendly and cheap, is one of the promising technological solutions. The article compares the characteristics of diatomite, diatomite-alginate granules and diatomite-alginate-Fe3O4 granules. Diatomite-alginate-Fe3O4 composites were synthesized by depositing magnetic iron oxide on alginate-diatomite granules. The process of synthesis and granulation of the composite adsorbent alginate-diatomite-magnetite was studied in this work. The process of applying the active magnetic phase of the adsorbent has been studied. All obtained samples were examined using electron microscopy, IR spectroscopy, X-ray phase analysis and derivatography. The dependence of the static strength of granules on the content of the solid phase (17–25 kPa) has been established. The thermal stability of the samples was studied. The adsorption of methylene blue anions from aqueous solutions has been studied. For the adsorbent alginate-diatomite and alginate-diatomite - Fe3O4, the degree of purification was 9599 %.

References

Rahimian, R., Zarinabadi, S. (2020). A review of studies on the removal of methylene blue dye from industrial wastewater using activated carbon adsorbents made from almond bark. Progress in Chemical and Biochemical Research, 3(3), 251–268.

doi:10.33945/sami/pcbr.2020.3.8

Shahadat, M., Isamil, S. (2018). Regeneration performance of clay-based adsorbents for the removal of industrial dyes: A review. RSC advances, 8(43), 24571–24587. doi: 10.1039/c8ra04290j

Frolova, L, Pivovarov A. (2016). Obtaining of brown pigments from concentrated waste water containing nickel. Chemistry & Chemical Technology, 10(2), 209– 212

Frolova, L., Kharytonov, M. (2019). Synthesis of magnetic biochar for efficient removal of Cr (III) cations from the aqueous medium. Advances in Materials Science and Engineering, 1 https://doi.org/10.1155/2019/2187132

Toor, M., Jin, B., Dai, S., & Vimonses, V. (2015). Activating natural bentonite as a cost-effective adsorbent for removal of Congo-red in wastewater. Journal of Industrial and Engineering Chemistry, 21, 653-661. https://doi.org/10.1016/j.jiec.2014.03.033

Wang, J., Cao, R., He, D., Saleem, A. (2021). Facile preparation of polyethyleneimine modified activated sludge-based adsorbent for hexavalent chromium removal from aqueous solution. Separation Science and Technology, 56(3), 498-506. https://doi.org/10.1080/01496395.2020.1728324

Baba, F., Benaliouche, F., Meknaci, R., & Boucheffa, Y. (2020). Water adsorption and antibacterial activity studies for characterization of Ca-LTA zeolite/diatomite adsorbents. Colloid and Interface Science Communications, 35, 100233. doi: 10.1016/j.colcom.2020.100233

Zhang, T., Wang, W., Zhao, Y., Bai, H., Wen, T., Kang, S., Komarneni, S. (2021). Removal of heavy metals and dyes by clay-based adsorbents: From natural clays to 1D and 2D nano-composites. Chemical Engineering Journal, 420, 127574. doi: 10.1016/j.cej.2020.127574

del Mar Orta, M., Martín, J., Santos, J. L., Aparicio, I., Medina-Carrasco, S., & Alonso, E. (2020). Biopolymer-clay nanocomposites as novel and ecofriendly adsorbents for environmental remediation. Applied Clay Science, 198, 105838.

doi: 10.1016/j.clay.2020.105838

Diagboya, P. N., Olu-Owolabi, B. I., Mtunzi, F. M., & Adebowale, K. O. (2020). Clay-carbonaceous material composites: Towards a new class of functional adsorbents for water treatment. Surfaces and Interfaces, 19, 100506.

https://doi.org/10.1016/j.surfin.2020.100506

Kausar, A., Iqbal, M., Javed, A., Aftab, K., Bhatti, H. N., & Nouren, S. (2018). Dyes adsorption using clay and modified clay: a review. Journal of Molecular Liquids, 256, 395–407. doi: 10.1016/j.molliq.2018.02.034

Xia, K., Liu, X., Chen, Z., Fang, L., Du, H., & Zhang, X. (2020). Efficient and sustainable treatment of anionic dye wastewaters using porous cationic diatomite. Journal of the Taiwan Institute of Chemical Engineers, 113, 8–15. doi: 10.1016/j.jtice.2020.07.020

Shen, T. M., Xu, H., Miao, Y., Ma, L. L., Chen, N. C., & Xie, Q. L. (2021). Study on the adsorption process of Cd (II) by Mn-diatomite modified adsorbent. Materials Letters, 300, 130087.

doi: 10.1016/j.matlet.2021.130087

Shi, S., Ocampo-Pérez, R., Lv, J., Liu, Q., Nan, F., Liu, X., ... & Feng, J. (2021). Diatomite cross-linked β-Cyclodextrin polymers: A novel vision of diatomite adsorbent for the removal of bisphenol A. Environmental Technology & Innovation, 23, 101602. https://doi.org/10.1016/j.eti.2021.101602

Gu, S., Kang, X., Wang, L., Lichtfouse, E., Wang, C. (2019). Clay mineral adsorbents for heavy metal removal from wastewater: a review. Environmental Chemistry Letters, 17(2), 629–654. https://doi.org/10.1007/s10311-018-0813-9

Zhang, H., He, Q., Zhao, W., Guo, F., Han, L., Wang, W. (2021). Superior dyes removal by a recyclable magnetic silicate@ Fe3O4 adsorbent synthesized from abundant natural mixed clay. Chemical Engineering Research and Design, 175, 272–282.

https://doi.org/10.1016/j.cherd.2021.09.017

Chen, L., Zhou, C. H., Fiore, S., Tong, D. S., Zhang, H., Li, C. S., Yu, W. H. (2016). Functional magnetic nanoparticle/clay mineral nanocomposites: preparation, magnetism and versatile applications. Applied Clay Science, 127, 143–163.

https://doi.org/10.1016/j.clay.2016.04.009

Fayazi, M. (2019). Facile hydrothermal synthesis of magnetic sepiolite clay for removal of Pb (II) from aqueous solutions. Analytical and Bioanalytical Chemistry Research, 6(1), 125–136.

Frolova, L.A. (2014). Production conditions of iron oxide black from pickle liquors. Metallurgical & Mining Industry, 4, 65–69.

Esvandi, Z., Foroutan, R., Peighambardoust, S. J., Akbari, A., & Ramavandi, B. (2020). Uptake of anionic and cationic dyes from water using natural clay and clay/starch/MnFe2O4 magnetic nanocomposite. Surfaces and Interfaces, 21, 100754.

Frolova L.; Derimova A.; Butyrina T. (2018). Structural and Magnetic Properties of Cobalt Ferrite Nanopowders Synthesis Using Contact Non-Equilibrium Plasma. Acta Physica Polonica A, 133(4), 1021–1023.

doi: 10.12693/APhysPolA.133.1003

Frolova, L., Pivovarov, A., Tsepich, E. (2016). Nonequilibrium plasma-assisted hydrophase ferritization in Fе2+–Ni2+–SO4 2−–OH− System. Nanophysics, Nanophotonics, Surface Studies, and Applications. Springer Proceedings in Physics, 183, 213–220.

Hariyadi, DM, & Hendradi, E. (2020). Optimization Performance and Physical Stability of Ciprofloxacin HCL-Ca Alginate Microspheres: Effect of Different Concentration of Alginate and CaCl. Technology, 10(1), 89–94.

Duez, J. M., Mestdagh, M., Demeure, R., Goudemant, J. F., Hills, B. P., & Godward, J. (2000). NMR studies of calcium‐induced alginate gelation. Part I—MRI tests of gelation models. Magnetic Resonance in Chemistry, 38(5), 324–330. doi: 10.1002/1097-458X(200005)38: 5<324::AID-MRC646>3.0.CO;2-1

Adzmi, F., Meon, S., Musa, M. H., & Yusuf, N. A. (2012). Preparation, characterisation and viability of encapsulated Trichoderma harzianum UPM40 in alginate-montmorillonite clay. Journal of microencapsulation, 29(3), 205–210.

Published

2022-07-25