SPECTROPHOTOMETRIC STUDY OF ZIRCONIUM WITH DINITROBENZENE-AZOPYROCATECHOL AND MULTI-LIGAND COMPLEXES WITH OP-10
DOI:
https://doi.org/10.15421/jchemtech.v30i3.252251Keywords:
Keywords: dinitrobenzene-azopyrocatechol, zirconium, Box-Behnken design, extraction.Abstract
The proposed method was used to study the multi-ligand complex of zirconium with 1.2-dinitrobenzene-azopyrocatechol and OP-10 following spectrophotometric methods. The optimization procedure was confirmed by the Box Behnken design. Maximum extraction of zirconium complex occurred in the pH range of 1.0–3.8.
The effect of temperature, solvents and their volumes on the absorption was studied. Under optimal conditions: 500 µL of chloroform was selected as extraction solvent, 400 µL of acetone was used as a dispersive solvent,pH was 2.0, λmax = 560 nm. The linear range, limit of detection and lgβk were found to be 0.04–5.8 µg mL–1, 0.08 µg mL–1 and 6.86, resp. Moreover, the effect of interference ions, which were present in water was investigated. The proposed method was applied for the determination of zirconium in various water samples.
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