LEAD DIOXIDE-PERFLUOROOCTANESULFONATE COMPOSITES: ELECTROSYNTHESIS AND APPLICATION

Authors

DOI:

https://doi.org/10.15421/jchemtech.v30i3.258525

Keywords:

potassium perfluorooctanesulfonate, lead dioxide, electrosynthesis, nitrate electrolyte, 4-chlorophenol

Abstract

The regularities of electrosynthesis, properties, and electrocatalytic activity of the composites lead dioxide-perfluorooctanesulfonate have been investigated. Comprehensive data on the regularities of PbO2 nucleation in the presence of perfluorooctane sulfonate in the deposition electrolyte are obtained. The kinetics of the deposition of composites in the presence of surfactant in the deposition electrolyte has been studied, it is shown that the effect of inhibiting of PbO2 deposition, which is evident more with increasing of fluorine-carbon chain length, no longer evident when the chain reaches eight carbon atoms. The morphology and phase composition of composites were studied. The influence of the composition of composites on the reaction of oxygen evolution and oxidation of 4-chlorophenol was studied.

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Published

2022-10-31

Issue

Vol. 30 No. 3 (2022): Journal of Chemistry and Technologies

Section

Electrochemistry

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