LOW-WASTE TECHNOLOGIES OF ION-EXCHANGE EXTRACTION OF PHOSPHATES FROM SOLUTION

Authors

  • Inna M. Trus National Technical University of Ukraine «Igor Sikorsky Kyiv Polytechnic Institute», Ukraine http://orcid.org/0000-0001-6368-6933
  • Yana P. Kryzhanovska National Technical University of Ukraine «Igor Sikorsky Kyiv Polytechnic Institute», Ukraine https://orcid.org/0000-0002-9747-969X
  • Mukola D. Gomelya National Technical University of Ukraine «Igor Sikorsky Kyiv Polytechnic Institute», Ukraine

DOI:

https://doi.org/10.15421/jchemtech.v31i1.262743

Keywords:

phosphates, ion exchange, regeneration solutions, struvite

Abstract

Excessive supply of biogenic substances with wastewater from industrial enterprises, in particular phosphorus, causes excessive eutrophication of natural water bodies, which leads to the qualitative depletion of water resources. The most promising method of water purification from phosphates is ion exchange. The process of sorption of phosphates on highly basic anionite in chloride and alkaline form is investigated in the present work. The processes of influence of competing anions on the efficiency of phosphate extraction were studied. It was established that the selectivity of the AV-17-8 anionite increases in the series of chlorides-phosphates-sulfates. It is shown that for regeneration of anionite in phosphate and phosphate-sulfate form it is advisable to use solutions of 10 % NH4Cl, 15 % NaCl, 6 % Na2CO3, 7% KOH, 6 % (NH4)2SO4. Methods for extracting phosphates from regeneration solutions have been developed making them suitable for reuse. To create waste-free processes, a method of extracting phosphates from water using AV-17-8 anionite and its regeneration has been proposed, which will allow extracting phosphates in the form of mineral fertilizers and repeatedly using regeneration solutions.

Author Biography

Inna M. Trus, National Technical University of Ukraine «Igor Sikorsky Kyiv Polytechnic Institute»

Docent of the Department of ecology and technology of plant polymers

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Published

2023-04-25

Issue

Vol. 31 No. 1 (2023): Journal of Chemistry and Technologies

Section

Chemical Technology

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