CHEMISORPTION OF FLAVONOIDS FROM CANADIAN GOLDENROD ON ALUMINUM OXIDE
DOI:
https://doi.org/10.15421/jchemtech.v30i3.262972Keywords:
flavonoids; rutin; aluminum oxide; chemisorption; reflectance spectra; colorimetryAbstract
The results of the study of sorption of flavonoids in aqueous and alcoholic extracts of inflorescences of canadian goldenrod with alumina are presented. The methods of reflectance spectroscopy in the visible range and colorimetry (CIE XYZ, CIE L*a*b* systems) were used to characterize plant raw materials, preparations of standard rutin in the solid phase, and adsorbates. According to the data of solid-phase spectrophotometry, the interaction occurred by chemisorption of flavonoids on the surface of the sorbent. The similar nature of the reflectance spectra of adsorbates from extracts and rutin, the predominant component of the flavonoid composition of the studied plant raw materials, was confirmed. The use of the first spectrum derivative proved to be a more effective method for identifying the formation of adsorption complexes in comparison with determining the position of the extended maximum in the reflectance spectra of adsorbates. The bathochromic shift of the minimum of the spectral band in the case of chemisorption is proposed as a diagnostic criterion. According to colorimetric measurements, chemisorption of flavonoids caused an increase in the conditional purity of color tone and yellowness index of adsorbates. For the comparative analysis of adsorbates, the total color difference was calculated with a division into component differences in lightness, chroma and hue angle. The possibility of using an environmentally safe solvent for the functionalization of a biocompatible sorbent has been confirmed. The obtained results can be used in the development of concentration, stabilization of flavonoids from extracts of medicinal plants, the creation of biohybrid materials, improvement of methods of solid-phase analysis of biologically active substances.
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