COPOLYMERS OF MALEIC ANHYDRIDE AND STYRENE AND ION-EXCHANGE FILM MATERIALS BASED ON THEM
DOI:
https://doi.org/10.15421/jchemtech.v30i4.268119Keywords:
maleic anhydride-styrene copolymer; ethylene-propylene oxide block copolymer; solvent; solubility parameter; static exchange capacity; gel fraction; swellingAbstract
In order to determine the influence of the nature of the solvent on the molecular weight, copolymers of styrene and maleic anhydride (SMA) and terpolymers of styrene, maleic anhydride and acrylonitrile (SMN) were synthesized. The synthesis was carried out by the method of radical polymerization in individual solvents or their mixtures, having solvent parameters according to Hildebrand δi in the range of 18.3÷20.55 MJ-0.5m-1.5. The research objects were selected due to the presence of reactive anhydride cycles in the polymer chains. It is shown that the degree of polymerization of the synthesized compounds can be estimated by the closeness of the contributions of the associative solubility parameters δa/δ to the corresponding solubility parameters of the polymer δ2 and the solvent δ1. The value of the solubility parameters was calculated based on the three-dimensional concept of the solubility parameter of M. Hansen and using the method of A. Askadskii.
On the basis of synthesized polymer compounds and commercial block copolymers of ethylene oxide and propylene oxide, film flexible materials with ion exchange properties were obtained, in which the static exchange capacity is (4.28÷6.37) meq/g. It was determined that the content of the gel fraction of the materials is (86÷97)% and depends on the nature of the solvent from which the films are obtained, and the increase in the content of the gel fraction is facilitated by the closeness of the δα/δ values of the solvent and SMA/SMN.
The ability of film materials to swell was investigated. It was determined that at pH > 6, the degree of swelling increases in leaps and bounds, and the dynamics of swelling and its maximum value depends on the static exchange capacity and the content of oxyethylene component links in the mesh structure.
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