ELECTRONO-CATALYTIC INTENSIFICATION COMBUSTION OF SOLID FUEL

Authors

DOI:

https://doi.org/10.15421/jchemtech.v31i3.285955

Keywords:

electrocatalysis; burning; intensification; coal; dielectric barrier discharge

Abstract

Coal is the most available energy resource and its consumption increases every year. Coal reserves, unlike oil and gas, are large. But not infinite. Therefore, there is already a question of creating technologies that would allow reducing the consumption of coal while preserving, and if possible, increasing the amount of energy obtained when burning it. For this, it is proposed to use the directed action of an artificially created low-temperature plasma with an ordered movement of "slow" electrons. A dielectric barrier discharge was used as a source of "slow" electrons. The use of an electrono-catalytic method of intensifying the combustion process of solid fuel allows to increase the output of volatile compounds with a heat of combustion higher than the heat of combustion of compounds, weakens bonds in the crystalline structure of the coke residue and increases the degree of fuel combustion.  This makes it possible to reduce coal consumption by up to 20 % with electricity consumption of 25–30 W·h per 1 kg of coal and increase the formation of volatile compounds for anthracite to 13.42 %, for gas coal to 24.9 %.

References

World Coal Reserves https://www.worldometers.info/coal/

Babiy, V.I., Kuvaev, Yu.F. (1986). [Combustion of coal dust and calculation of a pulverized coal torch]. Moscow, Russian Federation: Energoatomizdat (in Russian).

Khzmalyan, D. M., Kagan, Ya. A. (1976). [Theory of combustion and furnace devices.] Moscow, Russian Federation: Energy (in Russian)

Warnatz, Y., Maas, W., Dibble, R:. (2003). [Combustion. Physical and chemical aspects, modeling, experiments, formation of pollutants], Moscow, Russian Federation: Fikhmatlit. (in Russian).

Paraschiv, L. S., Serban, A., Paraschiv, S. (2020). Calculation of combustion air required for burning solid fuels (coal /biomass / solid waste) and analysis of fl ue gas composition. Energy, 6, 36–45. https://doi.org/10.1016/j.egyr.2019.10.016

Khatri, D., Gopan, A., Yang, Z., Adeosun, A., Axelbaum, R. (2019). Сharacterizing early stage sub-micron particle formation during pulverized coal combustion in a flat flame burner, Fuel, 258(15), 115995. https://doi.org/10.1016/j.egyr.2019.10.016

Wang, K., Han, T., Deng, J., Zhang, Y. (2022). Comparison of combustion characteristics and kinetics of Jurassic and Carboniferous-Permian coals in China, Energy, 254, B, 124315. https://doi.org/10.1016/j.energy.2022.124315

Avtaeva, S.V. (2009). [Barrier discharge. research and application]. Bishkek, Kyrgyzstan: Izd-vo KRSU. (in Russian).

Kogelschatz, U. (2003) Dielectric-barrier Discharges: Their History, Discharge Physics, and Industrial Applications. Plasma Chemistry and Plasma Processing, 23, (1), 1–46

Sharma, N.K, Misra, S, Varun, V, Pal, U.N. (2020) Experimental and simulation analysis of dielectric barrier discharge based pulsed cold atmospheric pressure plasma jet Physics of Plasmas 27, 113502. https://doi.org/10.1063/5.0018901

Vyazovik, V. M. (2023). [Electron-catalytic intensification of the mountain of gas-like fire]. Journal of Chemistry and Technologies, 31(1), 186–194. https://doi.org/10.15421/jchemtech.v31i1.271226 (in Ukrainian).

Uytdenhouwen, Y., Bal, K. M., Neyts, E. C., Meynen, V., Cool, P., Bogaerts, A. (2021) On the kinetics and equilibria of plasma-based dry reforming of methane. Chemical Engineering Journal. 405(1), 126630 https://doi.org/10.1016/j.cej.2020.126630

Jia, Z., Yang, N., Sun, L., Zhao, Y., Li W., Luan, J., Lyu, F., Zhang, L.C., Kruzic, J.J., Kai, J.J., Huang, J.C., Lu, J., Liu, C.T., Novel, А. (2020). Multinary Intermetallic as an Active Electrocatalyst for Hydrogen Evolution. Advanced Materials, 2000385. https://doi.org/10.1002/adma.202000385

Chen, J., Jin, Q., Li, Yi., Li, Y., Cui, Y., Wang, C., (2019). Design Superior Alkaline Hydrogen Evolution Electrocatalyst by Engineering Dual Active Sites for Water Dissociation and Hydrogen Desorption ACS Appl. Mater. Interfaces, 11(42), 38771–38778 https://doi.org/10.1021/acsami.9b13657

Uytdenhouwen, Y., Bal, K. M., Neyts, E. C., Meynen, V., Cool, P., Bogaerts, A. (2021). On the kinetics and equilibria of plasma-based dry reforming of methane. Chemical Engineering Journal, 405(1), 126630 https://doi.org/10.1016/j.cej.2020.126630

Stepanov, E.M., Dyachkov, B.G. (1968) [Ionization in flame and electric field]. Moscow, Russian Federation: Metallurgy. (in Russian)

He, J., Wen, X., Wu, L., Chen, H. (2022). Dielectric barrier discharge plasma for nanomaterials: Fabrication, modification and analytical applications. TrAC Trends in Analytical Chemistry, 156.

Li J., Ma, C., Zhu, S., Yu, F., Dai, B., Yang, D. (2019). A Review of Recent Advances of Dielectric Barrier Discharge Plasma in Catalysis. Nanomaterials, 9, 1428. https://doi.org/10.3390/nano9101428

Gorfinkiel, J.D. (2020). Electron collisions with molecules and molecular clusters. The European physical journal D, 7451. https://doi.org/10.1140/epjd/e2020-100550-7

Bogaerts, A., Zhang, Q. Z., Zhang, Y. R. , Laer, K. V., Wang, W. (2019). Burning questions of plasma catalysis: Answers by modelling. Catalysis Today, 337, 15. https://doi.org/10.1016/j.cattod.2019.04.077

Viazovyk, V. (2020). Electrocatalytic intensification of burning processes for hard and gaseous fuel. 3 International scientific and technical conference «Innovative development of resource-saving technologies and sustainable use of natural resources», Petrosani, Romania, 33–35.

Viazovyk, V., Stolyarenko, H., Vodianik, O. (2011) The alternative burning of coal. Nauka i studia, Chemia. 110–115.

Stolyarenko, H., Martsinyshyn, U., Viazovik, V. (2008). The alternative burning of hydrocarbon. Contributed Papes Internetional Workshop «Nonequilibrium Processes In Combustion And Plasma Based Technologies», 84–89

Stolyarenko, G. S., Viazovyk, V. N., Vodianik, O. V, Martsinyshyn, U.D, Badko, Y.U. Procede d'intensification de combustion d'un carburant solide. (2008). France Patent № 2 905 001 A1.

Yarovoi, R.V., Stolyarenko, G.S. (2013). Burning of coal and wood using electrocatalysis/ Moderrni vymozenosti vedy. Chemie a chemicka technologie. 65, 67–71.

Published

2023-10-28