OPTIMIZATION OF THE WASTEWATER PURIFICATION PROCESS FROM ORGANIC DYES USING THE FERRITE COMPOSITE
DOI:
https://doi.org/10.15421/jchemtech.v32i1.290728Keywords:
purification; wastewater; optimization; organic dyes; ferrite; kinetic equations; photocatalysis; sorptionAbstract
The relevance of the work is related to the solution of environmental problems arising from an increase in the amount of industrial waste water contaminated with organic dyes. The aim of the work was to optimize the process of wastewater treatment from organic dyes – methylene blue, methylviolet and Congo red, when using copper-zinc ferrite, taking into account the change in its mechanism over time and varying the process parameters: the concentration of dye solutions or ferrite mass. Quantitative kinetic characteristics of the process of cleaning solutions from organic dyes with a ferrite composite material of the composition Zn0.875Cu0.1Fe4.42O4 at various mass ratios n = "ferritic composite material: organic dye" are determined. It was proved that the purification of wastewater from organic dyes proceeds through the mechanisms of photocatalytic transformations and sorption and the kinetic characteristics of photocatalytic processes are an order of magnitude higher than those for the adsorption of dyes. An experimental database on wastewater treatment from dyes was created for each mechanism separately. The kinetic equations for the dependence of the concentration of dyes on time and the ratio n are calculated. The cleaning process was optimized for one or two process mechanisms progress while varying the process time, the initial dye concentration or ferrite mass, depending on the need to achieve certain process rates and the depth of cleaning. A scheme of a method for optimizing the process of wastewater treatment from organic dyes using a copper-zinc ferrite composite is proposed. The results are aimed at improving the efficiency and completeness of the purification process. A significant increase in the economic effect of the introduction of the cleaning process is predicted, since it is proposed to use waste from galvanic production for the production of copper-zinc ferrites.
References
Ismail M., Akhtar K., Khan M.I., Kamal T., Murad A. Khan, Abdullah M. (2019). Pollution, toxicity and carcinogenicity of organic dyes and their catalytic bio-remediation. Current Pharmaceutical Design, 25(34), 3645–3663. http://doi.org/10.2174/1381612825666191021142026
Vakili, M., Rafatullah, M., Salamatinia, B., Abdullah, A.Z., Ibrahim, M.H., Tan, K.B. et. al. (2014). Application of chitosan and its derivatives as adsorbents for dye removal from water and wastewater: A review. Carbohydrate Polymers, 113, 115–130. http://doi.org/10.1016/j.carbpol.2014.07.007
Md, J., Uddin, R., Ampiaw, E., Wontae, L. (2021). Adsorptive removal of dyes from wastewater using a metal-organic framework: A review. Chemosphere, 284, 131314. https://doi.org/10.1016/j.chemosphere.2021.131314
Francisco, J. Alguacil, F., Lopez, A. (2020). Adsorption Processes in the Removal of Organic Dyes from Wastewaters: Very Recent Developments. Wastewater Treatment, 17–32. http://doi.org/10.5772/intechopen.94164
Datsenko, V. V., Khobotova, E. B., Kolodiazhnyi, V. M., Lisin, D. O. (2022). The efficiency of purification of solutions from organic dyes with the use of copper-zinc ferrites. Journal of Chemistry and Technologies, 30(2), 184–191. http://doi.org/10.15421/jchemtech.v30i2.250987
Datsenko, V. V., Khobotova, E. B., Bielichenko, O. A., Korovianskyi, V. S. (2022). Polifunktsionalni materialy na osnovi ferytiv dlia ochyshchennia zabarvlenykh stichnykh vod. Visnyk Kharkivskoho natsionalnoho avtomobilno-dorozhnoho universytetu: zb. nauk. pr. 96, 113–120. http://doi.org/10.30977/BUL.2219-5548.2022.96.0.113
Solodovnik, T. V., Tolstopalova, N. M., Fomina, N. M., Yakymenko, I. K. (2019). Doslidzhennia protsesiv ochyshchennia zabarvlenykh rozchyniv pry vykorystanni neorhanichnykh koahuliantiv ta pryrodnoho flokulianta. Visnyk Cherkaskoho derzhavnoho tekhnolohichnoho universytetu, 3, 108–116. http://doi.org/10.24025/2306-4412.3.2019.167654
Li, H., Liu, S., Zhao, J., Feng, N. (2016). Removal of reactive dyes from wastewater assisted with kaolin clay by magnesium hydroxide coagulation process. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 494, 222–227. http://doi.org/10.1016/j.colsurfa.2016.01.048
Madani, M. (2021). Destruction of dyes in wastes of textile products. Technogenic and ecological safety, 10(2/2021), 58–63. http://doi.org/10.52363/2522-1892.2021.2.9
Kanakaraju, D., Glass, B. D., Oelgemöller, M. (2018). Advanced oxidation process-mediated removal of pharmaceuticals from water: a review. Journal of environmental management, 219, 189–207. http://doi.org/10.1016/j.jenvman.2018.04.103
Guo, J., Zhang, Q., Cai, Z., Zhao, K. (2016). Preparation and dye filtration property of electrospun polyhydroxybutyrate–calcium alginate/carbon nanotubes composite nanofibrous filtration membrane. Separation and Purification Technology, 161, 69–79. http://doi.org/10.1016/j.seppur.2016.01.036
Zou, H., Ma, W., Wang, Y. (2015). A novel process of dye wastewater treatment by linking advanced chemical oxidation with biological oxidation. Archives of Environmental Protection, 41(4), 33–39. http://doi.org/10.1515/aep-2015-0037
Kutsan, N. V., Vozniak, V. S., Ivanenko, I. M. (2019). Doslidzhennia adsorbtsiinykh vlastyvostei chystykh i kompozytnykh ferytiv. Scientific Journal «ScienceRise», 9–10(62–63), 32–37. http://doi.org/10.15587/2313-8416.2019.180982
Velusamy, S., Roy, A., Sundaram, S., Kumar Mallick, T. (2021). A Review on Heavy Metal Ions and Containing Dyes Removal Through Graphene Oxide-Based Adsorption Strategies for Textile Wastewater Treatment. Chemical Record (New York, N.Y.), 21, 1570–1610. http://doi.org/10.1002/tcr.202000153
Shestopalov, O. V., Hetta, O. S., Rykusova, N. I. Suchasni metody ochyshchennia stichnykh vod kharchovoi promyslovosti. Naukovo-praktychnyi zhurnal. Ekolohichni nauky, 2(25), 20–27. https://doi.org/10.32846/2306-9716-2019-2-25-4
Patil, D. J., Behera, S. N. (2023). Synthesis and characterization of nanoparticles of cobalt and nickel ferrites for elimination of hazardous organic dyes from industrial wastewater. Environ Sci Pollut Res, 30, 53323–53338. doi: https://doi.org/10.1007/s11356-023-26059-5
Pai, S., Kini, M.S., Selvaraj, R. (2021). A review on adsorptive removal of dyes from wastewater by hydroxyapatite nanocomposites. Environmental Science and Pollution Research International, 28, 11835–11849. https://doi.org/10.1007/s11356-019-07319-9
Hunge, Y. M., Mohite, V. S., Kumbhar, S. S., Rajpure, K. V., Moholkar, A. V., Bhosale, C. H. (2015). Photoelctrocatalytic degradation of methyl red using sprayed WO3 thin films under visible light irradiation. Journal of Materials Science, 26, 8404–8412. https://doi.org/10.1007/s10854-015-3508-z
Zoria, O., Ternovtsev, O., Zoria, D., Walery, M. (2019). Walery Advanced resource-saving copper wastewater treatment by ferritization. Ways to improve construction efficiency, 41, 148–162. https://doi.org/10.32347/2707-501x.2019.41.148-162
Ahmed, Hassoon Ali (2019). Treatment of wastewater contaminated with dyes using modified low-cost adsorbents. All rights reserved, 140, 326–336. https://doi.org/10.5004/dwt.2019.23513
Pan, P. L., Peng, B. (2022). Efficient Adsorption and Removal of Organic Dyes from Wastewater Using Magnetic UiO-66 Composites. Key Engineering Materials, 938, 171–176. https://doi.org/https://doi.org/10.4028/p-hcq3mq
Datsenko, V. V., Khobotova, E. B., Belichenko, O. A., Vankevich, O. V. (2021). Multifunctionality of composite material based on copper-zinc ferrite. Journal of Chemistry and Technologies, 29(4), 476–484. https://doi.org/10.15421/jchemtech.v29i4.240173
Datsenko, V. V., Khobotova, E. B., Vankevich, O. V., Tolmachov, S. M. (2022). Technically useful properties of copper-zinc ferrites. Functional Materials, 29(1), 62–71. https://doi.org/10.15407/fm29.01.62
Larin, V., Datsenko, V., Egorova, L., Hraivoronskaia, I., Herasymchuk, T. (2020). Physical and chemical properties of copper-zinc galvanic sludge in the process of thermal treatment. French-Ukrainian Journal of Chemistry, 9(1), 66–75.
Panteleimonov, A. V., Khrystenko, I. V., Ivanov, V. V. (2012). [Statistical and chemometric methods in chemistry: textbook] Kharkiv: KhNU named after V. N. Karazin. (In Ukrainian).
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