HIGH PURITY KRYPTON AND XENON PRODUCTION

Authors

DOI:

https://doi.org/10.15421/jchemtech.v31i4.292439

Keywords:

Krypton and high purity xenon, Burning out, Catalyst, Rectification, Adsorption, Purification of fluorine-containing air components

Abstract

The rare gases krypton and xenon are valuable gas products. The main industrial source of rare gases is atmospheric air. The presented work examines the features of rectification and adsorption-distillation technologies for the production of krypton and xenon. In the process of producing high-purity inert gases, together with Kr and Xe, air components similar in properties to them are enriched. Methods for purifying intermediate products and pure inert gases from microimpurities have been studied. Particular attention is paid to the purification of krypton and xenon from perfluorides

References

Bondarenko, V. L., Simonenko, Yu. M. (2013). [Cryogenic technologies of rare gas extraction]. Odessa, «Astroprint» (in Russian)

Bondarenko, V. L., Losyakov, N. P., Dyachenko, O. V. (2017). [Krypton and xenon market. Economic aspects of krypton-xenon mixture processing technology]. Tekhnicheskie gazy – Industrial Gases, 17(5), 12-22 (in Russian)

Bondarenko, V. L., Losyakov, I. A., Diachenko, O. V. (2020). Economic Aspects of Krypton and Xenon Production Technology. Chemical and Petroleum Engineering, 56 (3-4), 263-271.

https://doi.org/10.1007/s10556-020-00768-x

Bondarenko, V. L., Kislyy, A. N., Stefanovskiy, A. N., Dyachenko O. V. (2014). [The experience in obtaining krypton and xenon of high-purity]. Tekhnicheskie gazy – Industrial Gases, 14(2), 49-56 (in Russian).

https://doi.org/10.18198/j.ind.gases.2014.0722

Bondarenko. V. L., Simonenko. Yu. M., Korzh. Ye. G. (2013). [Improvement of installations for heavy rare gases extraction]. Tekhnicheskie gazy – Industrial Gases, 13(5), 25-34 (in Russian).

https://doi.org/10.18198/j.ind.gases.2013.0694

Bondarenko, V. L., Losyakov, N. P., Losyakov, I. A., Simonenko, Yu. M., Vigurzhinskaya, S. Yu., Dyachenko T. V. (2011). [New technologies extraction concentrates of rare gases]. Tekhnicheskie gazy – Industrial Gases, 11(1), 42-52 (in Russian).

https://doi.org/10.18198/j.ind.gases.2011.0539

Bondarenko, V. L., Kislyy, A. N., Dyachenko, O. V. (2016). [High purity krypton and xenon. purification from micro impurities]. Tekhnicheskie gazy – Industrial Gases, 16(2), 39-53 (in Russian).

https://doi.org/10.18198/j.ind.gases.2016.0817

Symonenko, O. Yu. (2011). [Prospects for production of argon and rare gases from ammonia by-products]. Kholodilnaya tehnika i tekhnologiya - Refrigeration engineering and technology, 5, 5-10 (in Russian).

Symonenko, O. Yu. (2011). [Cryogenic technologies for processing of blow-off streams of ammonia production]. Kholodilnaya tekhnika i tekhnologiya - Refrigeration engineering and technology, 6, 4-11 (in Russian).

Losyakov, I. A. (2007). [Analysis of the operation of the unit for obtaining xenon-nitrogen mixture from primary krypton concentrate by the method of low-temperature adsorption]. Kholodilnaya tekhnika i tekhnologiya - Refrigeration engineering and technology, 3(107), 5-12 (in Russian).

Bondarenko, V. L., Losyakov, N. P., Grafov, A. P. Losyakov, I. A. (2007). [Modernization of adsorption unit for reception of xenon-nitrogen mixture from primary krypton concentrate]. Tekhnicheskie gazy – Industrial Gases, 7(2), 35-39 (in Russian).

https://doi.org/10.18198/j.ind.gases.2007.0336

Bondarenko, V. L., Losyakov, N. P., Savinov, M. Yu., Volyinskiy, B. I., Bronshteyn, A. S., Poznyak, V. E. (2005). [Highly effective installation «Chrom-3» for extracting krypton-xenon mixture]. Tekhnicheskie gazy – Industrial Gases, 5(2), 31-35 (in Russian).

https://doi.org/10.18198/j.ind.gases.2005.0165

Savinov, M. Yu., Arharov, A.M., Poznyak, V. E., Bondarenko, V.L. (2007). Development and creation of an efficient Khrom-3 unit for preparing krypton-xenon mixtures. Chem. Petrol. Eng., 43, 259-569.

https://doi.org/10.1007/s10556-007-0047-3

Bondarenko, V. L., Kupriyanov, M. Yu., Ustyugova, T. G., Verhovnyiy, A. I., Stefanovskiy, A. N. (2019). Universal research cryogenic unit for xenon production. Chemical and petroleum engineering, 54, 806-814.

https://doi.org/10.1007/s10556-019-00554-4

Lemmon, E. W, Huber, M. L, McLinden, M. O. (2009). NIST Reference Fluid Thermodynamic and Transport Properties (REFPROP. Version 9.1): [U.S. Department of Commerce] National Institute of Standards and Technology, Gaithersburg, Maryland.

Wordl Steel Assotiation https://worldsteel.org/

Masterh, S.-G,. J. (1977). Dampf-Flüssig-Gloichgpwichtsdaten der Systeme Ar-N2, Kr-Ar, Kr-N2 und Xe-Kr sowie Löslichkeitsgrenzen des festen Xenons und des festen Kryptons in flüssigen Luftcomponenten. Ber. Kernforschungsanlage Jülich, Vol. 1145-1380(VI), 1-113.

Lyudmirskaya, G. S., Barsukova, T. A., Bogomolnyiy, A. M. (1977). [Liquid-vapour equilibrium. Handbook.] Khimiya – Chemistry, 336 p.

Aynshteyn, V. G., Zaharov, M. K. (2001). [Multicomponent rectification (principle and procedural schemes)]. Khimicheskaya promyshlennost - Chemical industry, 6, 39-47.

Fainshtein, V. I. (2008). [Results of monitoring the hydrocarbons content at technological flow of liquid oxygen of asp, equipped by blocks of complex air cleaning]. Tekhnicheskie gazy – Industrial Gases, 8(5), 59-64 (in Russian).

https://doi.org/10.18198/j.ind.gases.2008.0395

Bondarenko, V. L., Losyakov, N. P., Vorotyntsev, V. B., Mamrenko, V. A., Dzyuzyura, Ya. V., Vinnik, A. A. (2010). Experimental determination of tetrafluoromethane and hexafluoroethane accumulation in Khrom-3 krypton–xenon mixture producing equipment. Chemical and petroleum engineering, 46, 468-473.

https://doi.org/10.1007/s10556-010-9361-2

Tomas Ch. (1973). [Industrial catalytic processes and efficient catalysts]. In Rubinshtein, A. M.(ed.), Moscow: Mir.

Morozov, V. S., Morozov, D. V. (2003). [Adsorption purification of liquid oxygen from nitrous oxide]. Tekhnicheskie gazy – Industrial Gases, 3(2), 55-57 (in Russian).

https://doi.org/10.18198/j.ind.gases.2003.0086

Arkharov, A. M., Savinov, M. Yu., Bondarenko, V. L., Kolpakov, M. Iu., Vorotyntsev, V. B. (2005). [Adsorption low-temperature purification of krypton from tetrafluoromethane impurities]. Kholodilnaya tekhnika i tekhnologiya - Refrigeration engineering and technology, 10, 24-27 (in Russian).

Arkharov, A. M., Savinov, M. Yu., Bondarenko, V. L., Kolpakov, M. Iu., Vorotyntsev, V. B. (2005). Adsorption purification of xenon to remove hexafluoroethane impurities. Chem. Petrol. Eng. 41, 434–438.

https://doi.org/10.1007/s10556-005-0135-1

Adamov, V. S., Yatkin, V. A. (2007). Purification of krypton-xenon mixture from fluorine-containing gases. Russ. J. Phys. Chem., 81, 1005–1006.

https://doi.org/10.1134/S0036024407060301

Kolpakov, M. Yu. (2007). [Study of xenon adsorption dynamics on industrial sorbents and development of technology for xenon-containing mixture production at air separation plants](Unpublished PhD. thesis), Bauman Moscow State Technical University, – Moscow.

Timofeev, Yu. D., Izmajlov, V. R., Adamov V. S., Vostrikov, S. N., Utkin, V. N., Yatkin V. A. (2006). [Modernization and commissioning of krypton and xenon producing plant]. Tekhnicheskie gazy – Industrial Gases, 6(2), 43-46 (in Russian).

Savinov M. Yu. (2008). [Study of working processes and development of modern cryogenic technologies in the krypton and xenon production process]. (Unpublished doctoral dissertation), St. Petersburg State University of Low Temperature and Food Technologies. St. Petersburg.

Downloads

Published

2024-01-26

Issue

Section

Industrial gases. Chemical engineering