PREPARATION AND PROPERTIES OF COBALT-CONTAINING NITRIFICATION INHIBITORS
DOI:
https://doi.org/10.15421/jchemtech.v32i2.297927Keywords:
nitrogen; cobalt; dicyandiamide; nitrification; complex; 4-amino-1,2,4-triazole.Abstract
Dicyandiamide (DCD) and 4-amino-1,2,4-triazole (ATC) are nitrification inhibitors (NIs) that are widely used in agriculture. There are practically no studies related to their combination as part of a complex with «biometal», which, in our opinion, will have greater effectiveness. The aim of this work is the synthesis of new cobalt-containing complex compounds, determination of their structure, composition and biological activity. Four substances were synthesized with different ratios of ligands (ATC and DCD). Their solubility in water, a KAS-28 : water mixture, and commercial KAS-28 was established. A study of thermal behavior was carried out with the establishment of the most likely type of complex. Infrared spectroscopy proved 1,2-coordination of ATС via N1 and N2 atoms with a cobalt atom. The addition of DCD is carried out through the C≡N group. The content of Co(II) in substances is established. In laboratory conditions, the dynamics of changes in the number of NH4+ and NO3– ions were investigated and the degree of nitrification inhibition was calculated.
References
Fan, D., He, W., Smith, W.N., Drury, C.F., Jiang, R., Grant, B.B., Shi, Y., Song, D., Chen, Y., Wang, X., He, P., Zou, G. (2022). Global evaluation of inhibitor impacts on ammonia and nitrous oxide emissions from agricultural soils: A meta-analysis. Global Change Biology, 28(17), 5121–5141. https://doi.org/10.1111/gcb.16294
Meng, X., Li, Y., Yao, H., Wang, J., Dai, F., Wu, Y., Chapman, S. (2020). Nitrification and urease inhibitors improve rice nitrogen uptake and prevent denitrification in alkaline paddy soil. Applied Soil Ecology, 154, 103665. https://doi.org/10.1016/j.apsoil.2020.103665
Di, H.J., Cameron, K.C. (2005). Reducing environmental impacts of agriculture by using a fine particle suspension nitrification inhibitor to decrease nitrate leaching from grazed pastures. Agric Ecosys Environ, 109(3-4), 202–212. https://doi.org/10.1016/j.agee.2005.03.006
Yin, M., Gao, X., Kuang, W., Zhang, Y. (2023). Meta-analysis of the effect of nitrification inhibitors on the abundance and community structure of N2O-related functional genes in agricultural soils. Science of The Total Environment, 12(7), 1–13. https://10.1016/j.scitotenv.2022.161215
Zhou, X., Wang, S., Ma, S., Zheng, X. (2020). Effects of commonly used nitrification inhibitors dicyandiamide (DCD), 3,4-dimethylpyrazole phosphate (DMPP), and nitrapyrin on soil nitrogen dynamics and nitrifiers in three typical paddy soils. Geoderma, 380, 7294. https://doi.org/10.1016/j.geoderma.2020.114637
Li, J., Wang, W., Wang, W., Li, Y. (2022). The Ability of Nitrification Inhibitors to Decrease Denitrification Rates in an Arable Soil. Agronomy, 12(11), 2749. https://doi.org/10.3390/agronomy12112749
Tindaon, F., Benckiser, G., Gottlieb Ottow, J.C. (2011). Side Effects of Nitrification Inhibitors on Non Target Microbial Processes in Soils. J. Trop Soils, 16(1), 7–16. https://doi.org/10.5400/jts.2011.16.1.7
Alonso-Ayuso, M., Gabriel, J.L., Quemada, M. (2016) Nitrogen use efficiency and residual effect of fertilizers with nitrification inhibitors. European Journal of Agronomy, 80, 1–8. https://doi.org/10.1016/j.eja.2016.06.008
He, Т., Xie, D., Ni J., Li, Z., Li, Z. (2020). Effect of Cobalt, Cadmium and Manganese on Nitrogen Removal Capacity of Arthrobacter arilaitensis Y-10. Water, 12(1701), 1–12. https://doi.org/10.3390/w12061701
Kapustyan, A., Cherno, N. (2017) Chelate forms of biometalls. Theoretical aspects of obtaining and characteristics. Food Science and Technology, 11(1), 37–49. https://doi.org/10.15673/fst.v11i1.297
Ning, J., Ai, S., Cui, L. (2018). Dicyandiamidehas more inhibitory activities on nitrification thanthiosulfate. PLoS ONE, 13(8), 1–18. https://doi.org/10.1371/journal.pone.0200598
Aulakh, M.S., Singh, K., Doran, J.W. (2001). Effects of 4-amino-1,2,4-triazole, dicyandiamide and encapsulated calcium carbide on nitrification inhibition in a subtropical soil under upland and flooded conditions. Biol Fertil Soils, 33(3), 258–263. https://doi.org/10.1007/s003740000317
Nanayakkara, D., Prashantha, M.A.B., Fernando, T.L.D., Dissanayake, C.K., Karunarathna, B. (2023). Detection and quantification of dicyandiamide (DCD) adulteration in milk using infrared spectroscopy: A rapid and cost-effective screening approach. Food and Humanity, 1, 1472–1481. https://doi.org/10.1016/j.foohum.2023.10.013
Casali, L., Feiler, T., Heilmann, M., Braga, D., Emmerling, F., Grepioni, F. (2022). Too much water? Not enough? In situ monitoring of the mechanochemical reaction of copper salts with dicyandiamide. Cryst Eng Comm, 24, 1292-1298. https://doi.org/10.1039/D1CE01670A
Mahdi Salih, M., Irzoqi, A. (2018). Synthesis and Characterization Complexes of Ni(II) that Contain Cyanoguanidine and Phosphines Ligands. Tikrit Journal of Pure Science, 23(1), 92–101. https://doi.org/10.25130/tjps.23.2018.014
Du, J., Liu, X., Zhang, J., Liu, Y., Zhu, E., Che, G., Jia, M. (2019). Facile Synthesis of a Polycatenane Compound Basedon Ag-triazole Complexes and Phosphomolybdic Acid for the Catalytic Epoxidation of Olefins with Molecular Oxygen. Catalysts, 9(7), 1–13. https://doi.org/10.3390/catal9070568
Trivedi, M. K., Tallapragada, R. M., Branton, A. (2015). Characterization of Physical, Spectral and Thermal Properties of Biofield Treated 1,2,4-Triazole. Journal of Molecular Pharmaceutics & Organic Process Research, 3(2), 1–6. https://doi.org/10.4172/2329-9053.1000128
Малоок, М.В., Матросов, О.С., Рула, І.В. (2023). Комплексні сполуки цинку(ІІ) як інгібітори нітрифікації. Питання хімії та хімічної технології, 3(148), 94-102. https://doi.org/10.32434/0321-4095-2023-148-3-94-102
Bin, Z., Shang-Hao, L. (2020). Thermal stability assessment of 4-amino-1,2,4-triazole picrate using thermal analysis method. J. of Thermal Analysis and Calorimetry, 139(2), 2155–2163. https://doi.org/10.1007/s10973-019-08614-w
Li, Q., He, Y., Peng, R.F. (2015). Graphitic carbon nitride (g-C3N4) as a metal-free catalyst for thermal decomposition of ammonium perchlorate. RSC Advances, 5(31), 24507–24512. https://doi.org/10.1039/C5RA01157D
Wang, W.T., Liu, S.H., Cheng, Y.F. Wang, Y., Yu, C.F. (2022). Evaluation of thermal decomposition characteristics and potential hazards of 1-n-butyl-3-methylimidazolium dicyanamide by STA, ARC, and TG-FTIR. J. of Thermal Analysis and Calorimetry, 147(20), 11127–11137. https://doi.org/10.1007/s10973-022-11333-4
Jiménez-Calvo, P. (2019). Synthesis, characterization, and performance of g-C3N4 based materials decorated with Au nanoparticles for (photo) catalytic applications. Université de Strasbourg, 324.
Hassen, S., Arfaoui Y., Filinchuk, Y., Klein, A. (2023). A cationic Co(II) coordination polymer 1∞[Co(μ-L)(μ-Cl)(H2O)2]+ with the 4-amino-4H-1,2,4-triazole ligand: structure, thermal behavior, and antimicrobial activity. Inorganica Chimica Acta, 557(7), 1–24. https://doi.org/10.1016/j.ica.2023.121664
Rwei, S.P., Lin, Y.T., Yeh, S.K. (2014). A flame-retardant copper-clad laminate composite made of (metallocenebased cyclic olefin copolymer/glass) / cresol-novolak epoxy with low dielectricity. Textile Research Journal, 85(5), 524–534. https://doi.org/10.1177/0040517514548750
Taggert, B.I., Walker, C., Chen, D., Wille, U. (2021). Substituted 1,2,3-triazoles: a new class of nitrification inhibitors. Scientific Reports, 13(8), 1–18. https://doi.org/10.1038/s41598-021-94306-1
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