PHYSICO-CHEMICAL STUDY, MOLECULAR MODELING AND ANTIBACTERIAL ACTIVITY OF α- AND β-ANOMERS OF XYLOSE ESTERS
DOI:
https://doi.org/10.15421/jchemtech.v33i1.312010Keywords:
Xylose ester; anomers; surface properties; modeling; antibacterial activityAbstract
Non-ionic surfactants obtained from renewable resources represent a new challenge in biotechnology and have a range of applications in many industries. In this context, the α- and β-anomers of synthesized D-xylose-based bio-surfactants with various chain length were easily separated and characterized through analytical methods. Their surface and emulsifying properties were evaluated. To study the reactivity of the two anomers of synthetized biosurfactants, the spatial conformations of the prepared acyl-xylopyranose were obtained by molecular modeling with Gaussian 9 software using the density functional theory method. Compounds α are the softest so more reactive than the β ones. The antibacterial activity of sugar fatty acid ester anomers was also studied. The results obtained indicate the importance of anomeric form and chain length for the stability of the synthesized compounds.
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