STUDY ON PARTICIPATION OF CAMELINA SATIVA SEEDCAKE EXTRACT COMPONENTS IN THE SYNTHESIS OF CERIUM DIOXIDE NANOPARTICLES

Authors

DOI:

https://doi.org/10.15421/jchemtech.v32i4.316488

Keywords:

Camelina sativa, extract, nanoparticles, cerium oxide, «green» synthesis

Abstract

Aim. To evaluate the possibility of using the extract from Camelina sativa seedcake for the green synthesis of cerium oxide nanoparticles (CeO2-NPs), to investigate the composition of this extract, to elucidate which components participate in the formation of CeO2-NPs, to characterize the CeO2-NPs obtained. Methods. High-performance liquid chromatography and matrix-assisted laser desorption/ionization mass spectrometry were used to identify the components of Camelina sativa seedcake extract and of the reaction mixture after removal of CeO2-NPs. X-ray diffraction, thermal desorption of argon, transmission electron microscopy, dynamic light scattering were used to characterize the CeO2-NPs obtained. Results. The main components of the extract are phenolic acids and/or their derivatives (ferulic acid, hydroxycavic acid, sinapin), flavonoids (rutin, quercetin, quercetin-2-O-apiosyl-3-O-rutinoside), glucosinolates (glucoarabin, glucocamelinin, gluconesliapaniculatin), unsaturated fatty acids and their esters. The majority of phenolic acids and flavonoids as well as some portion of glucosinolates participate in the formation of nanoparticles. The obtained CeO2-NPs have a cubic crystalline structure with an average crystallite size of 23 nm, while the largest percentage of nanoparticles has a diameter of 30÷50 nm. Conclusions. The possibility of using the extract from Camelina sativa seedcake for the green synthesis of CeO2-NPs is shown and the main components of the extract were identified. The majority of identified components of the extract participate in the formation of CeO2-NPs. The obtained CeO2-NPs are crystalline and their size allows them to be used in various biomedical applications.

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Published

2025-01-23

Issue

Vol. 32 No. 4 (2024): Journal of Chemistry and Technologies

Section

Special issue International Chemical Hub Forum

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