STUDY OF THE DYNAMICS OF OXIDATION OF VEGETABLE OILS TO PROLONG THE STORAGE

Authors

DOI:

https://doi.org/10.15421/jchemtech.v33i2.323958

Keywords:

vegetable oil, peroxide number, anisidine number, oxidation, totox index

Abstract

Aim. To investigate the oxidation processes of edible vegetable oils: unrefined flaxseed oil, refined high-oleic sunflower oil, and refined traditional sunflower oil. The purpose of the study was to examine and analyze the dynamics of oxidation processes in vegetable oils and their impact on the shelf life of food products containing these oils. Methods. The oxidation of oils was analyzed using the peroxide number indicator, which showed that the ratio of the average rates of peroxide compound accumulation in unrefined flaxseed oil, refined traditional sunflower oil, and refined high-oleic sunflower oil was 54 : 43 : 1, indicating a proportional relationship with their degree of unsaturation. The primary oxidation products formed in the oil are unstable, leading to the formation of new radical compounds and more stable secondary oxidation products. The study included the determination of carbonyl compounds, characterized by the anisidine number. Results. The research revealed an important feature of unrefined flaxseed oil oxidation: the anisidine number increased more rapidly compared to refined traditional and high-oleic sunflower oils. This indicates the relative instability of unrefined flaxseed oil hydroperoxides, which undergo destruction to form carbonyl and other secondary compounds. Due to its high content of polyunsaturated fatty acids, unrefined flaxseed oil is vulnerable to oxidation and mixing it with refined high-oleic sunflower oil can enhance the oxidative stability of food products. Conclusions. The results highlight the importance of considering the dynamics of oxidation processes when selecting vegetable oils for food products and suggest that mixing different types of oils can improve their oxidative stability and the overall stability of food products.

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Published

2025-07-15