PREPARATION AND STUDY OF ACID-BASE AND ION EXCHANGE PROPERTIES OF RICE HUSK BIOCHAR
DOI:
https://doi.org/10.15421/jchemtech.v33i3.330378Keywords:
rice husk, biochar, pyrolysis, microwave irradiation, thermochemical conversion, acid-base properties, ion exchange propertiesAbstract
Odesa region is a leader in Ukraine in rice production, which makes the issue of utilizing rice by-products particularly relevant. Rice husks are considered as a promising raw material for the production of biochar. The aim of this study is to synthesise biochar, which is used as a carrier for immobilizing the isolated soil microbial complex for the treatment of oil-containing wastewater, and to study its acid-base and ion-exchange characteristics. The analysis of potentiometric titration curves indicates the contribution of different ionized groups to the general properties of biochar, which allows it to be classified as a polyfunctional ion exchanger. It is proved that due to the properties of ampholytes, biochar can be used as a matrix for immobilization of microbial complexes, capable of acting as a buffer by regulating the pH level.
References
Tkachenko, A., Sagdeeva, O., Krusir, G., Malovanyy, M., Vitiuk, A. (2024). Buckwheat husk biochar: preparation and study of acid-base and ion-exchange properties. Journal of Chemistry and Technologies, 32(3), 1–12. doi: 10.15421/jchemtech.v32i3.306261
Sokolova, T., Krusir, G., Shunko, H., Korkach, H., Makarova, O., Tolstykh, V., Sokolova, V. (2024). Preparation and study of acid-base and ion-exchange properties of biochar from waste coffee grounds. Ecological Engineering & Environmental Technology, 25(11), 399–409.doi.org/10.12912/27197050/193052
Oliveira, G, Gevaerd, A., Mangrich, A., Marcolino-Junior, L., Bergamini, M. (2021). Biochar obtained from spent coffee grounds: Evaluation of adsorption properties and its application in a voltammetric sensor for lead (II) ions. Microchemical Journal, 165, 106114. doi.org/10.1016/j.microc.2021.106114
Yu, Y.; Yang, B.; Petropoulos, E.; Duan, J.; Yang, L.; Xue, L. (2022). The Potential of Biochar as N Carrier to Recover N from Wastewater for Reuse in Planting Soil: Adsorption Capacity and Bioavailability Analysis. Separations, 9(11), 337. doi.org/10.3390/separations9110337.
Sokolova, T., Krusir, G., Hugi, Ch., Breitenmoser, L., Yeleuova, E., Daldabayeva, G., Malovanyy, M., Korkach, O., Sokolova, V. (2024). Study of the effect of biochar from spent coffee grounds on anaerobic digestion of food waste from the restaurant industry. Journal of Chemistry and Technologies, 32(2), 371–381. https://doi.org/10.15421/jchemtech.v32i2.297925
Godlewska, P.; Schmidt, H., Ok, Y., Oleszczuk, P. (2017). Biochar for composting improvement and contaminants reduction. A review. Bioresour. Technol., 246, 193–202. doi.org/10.1016/j.biortech.2017.07.095.
Sokolova, T., Krusir, G., Petrushka, I., Malovanyy, M., Sokolova, V. (2025). Chemical and structural characteristics and sorption properties biochar from waste coffee grounds. Journal of Chemistry and Technologies, 33(1), 123–135. doi.org/10.15421/jchemtech.v33i1.316519
Qasim, W., Lee, M., Moon, B., Okyere, F., Khan, F., Mohammad, N., Kim, H. (2018). Composting of chicken manure with a mixture of sawdust and wood shavings under forced aeration in a closed reactor system. Intern. Journ. Recycl. Organ. Waste Agricult., 7(5), 261–267. doi.org/10.1007/s40093-018-0212-z.
Tkachenko, A., Sahdieieva, O., Krusir, G., Malovanyy, M. (2025). Study of Sorption Properties of Buckwheat Husk Biochar. Advances in Science and Technology, 162, 31–40. doi:10.4028/p-8UfFtt
Skliar, V., Krusir, G., Zakharchuk, V., Kuznecova, I., Malovanyy, M. (2020). Study of the physical and chemical characteristics of an immobilized lipase in the hydrolysis of fat waste. Ecological Questions, 31(3), 1644–7298. doi.org/10.12775/EQ.2020.019
Krusir, G., Sagdeeva, O., Malovanyy, M., Shunko, H., Gnizdovskyi, O. (2020). Investigation of Enzymatic Degradation of Solid Winemaking Wastes. J. Ecol. Eng., 21(2), 72–79. doi.org/10.12911/22998993/116345
Ramola, S., Belwal, T., Li, C., Liu, Y., Wang, Y., Yang, S., Zhou, C. (2021). Preparation and application of novel rice husk biochar–calcite composites for phosphate removal from aqueous medium. Journ. of Clean. Product., 299, 126802. https://doi.org/10.1016/j.jclepro.2021.126802
Krusir, G., Korkach, H., Pylypenko, L., Khomych, G. (2024). Methodological bases for determining the biologicality of food products for environmental labelling. Journal of Chemistry and Technologies, 32(4), 1016–1029. doi: 10.15421/jchemtech.v32i4.312575
Krusir, G., Zakharchuk, V., Sevastyanova, E., Pylypenko, L., Moshtakov, S. Isolation of Alfalfa Seed Trypsin Inhibitor using Affinity Chromatography. Journal of Chemistry and Technologies, 28(3), 269–277. doi.org/10.15421/08202803
Ebrahimzadeh, O., Shorafa, M., Zolfaghari, A., Toolarood, A. (2020). The effect of biochar on severity of soil water repellency of rude oil-contaminated soil. Environ. Science Pollut. Res., 27, 6022–6032. doi.org/10.1007/s11356-019-07246-9.
Zhou, X., Zhou, J., Liu, Y., Guo, J., Jialin, R., Zhou, F. (2018). Preparation of iminodiacetic acid-modified magnetic biochar by carbonization, magnetization and functional modification for Cd(II) removal in water. Fuel, 233, 469–479. doi.org/10.1016/j.fuel.2018.06.075.
Dziedzic, K., Górecka, D., Kucharska, M., Przybylska, B. (2012). Influence of technological process during buckwheat groats production on dietary fibre content and sorption of bile acids. Food Res. Intern., 47(2), 279–283. doi.org/10.1016/j.foodres.2011.07.020.
Song, C., Ma, C., Xiang, D. (2019). Variations in Accumulation of Lignin and Cellulose and Metabolic Changes in Seed Hull Provide Insight into Dehulling Characteristic of Tartary Buckwheat Seeds. Intern.l Journ. Molec. Scienc., 20(3), 524. doi.org/10.3390/ijms20030524.
Samal, K., Dash, R., Bhunia, P. (2017). Treatment of wastewater by vermifiltration integrated with macrophyte filter: A review. Journ. Environ. Chemic. Engin., 5(3), 2274–2289. doi.org/10.1016/j.jece.2017.04.026.
Kochubei, V., Yaholnyk, S., Bets, M., Malovanyy, M. (2020). Use of Activated Clinoptilolite for Direct Dye-Contained Wastewater Treatment. Chem. Chem. Technol., 14(3), 386–393. doi.org/10.23939/chcht14.03.386.
Tymchuk, I., Malovanyy, M., Shkvirko, O., Yatsukh, K. (2021). Sewage Sludge as a Component to Create a Substrate for Biological Reclamation. Ecol. Eng. Environ. Technol., 22(4), 229–237. doi.org/10.12912/27197050/137863
Tymchuk, I., Malovanyy, M., Shkvirko, O., Chornomaz, N., Popovych, O., Grechanik, R., Symak, D. (2021). Review of the global experience in reclamation of disturbed lands. Inzyn. Ekolog., 22(1), 24–30. doi.org/10.12912/27197050/132097
Tymchuk, I., Malovanyy, M., Shkvirko, O., Zhuk, V., Masikevych, A., Synelnikov, S. (2020). Innovative creation technologies for the growth substrate based on the man-made waste - perspective way for Ukraine to ensure biological reclamation of waste dumps and quarries. Int. J. Foresight and Innovation Policy, 14(2/3/4), 248–263. doi.org/10.1504/IJFIP.2020.111239.
Vakal, S., Yanovska, A., Vakal, V., Artyukhov, A., Shkola, V., Yarova, T., Dmitrikov, V., Krmela, J., Malovanyy, M. (2020). Minimization of Soil Pollution as a Result of the Use of Encapsulated Mineral Fertilizers. Journal of Ecological Engineering, 22(1), 221–230. doi.org/10.12911/22998993/128965.
Jara, P., Schoeninger, V., Dias, L., Siqueira, V., Lourente, E. (2022). Physicochemical quality characteristics of buckwheat flour. Engen. Agrícol., 42(4), e20210026. doi.org/10.1590/1809-4430-Eng.Agric.v42n4e20210026/2022.
Sharma, A., Pareek, V., Zhang, D. (2015). Biomass Pyrolysis - A Review of Modelling, Process Parameters and Catalytic Studies. Renew. Sust. Energ. Rev., 50(9), 1081-1096. doi.org/10.1016/j.rser.2015.04.193.
Krusir, G., Pylypenko, L., Sevastyanova, E., Mazurenko, K., Moshtakov, S., Shunko, H., Vitiuk, A., Shpyrko, T., Zdoryk, O. (2023). Isolation and characterization of pancreatic lipase inhibitor from rapeseed seeds. Journal of Chemistry and Technologies, 31(2), 255–270 doi: 10.15421/jchemtech.v31i2.279214
Yaashikaa, P., Kumar, P., Varjani, S., Anbalagan, S. (2019). Advances in production and application of biochar from lignocellulosic feedstocks for remediation of environmental pollutants. Bioresour. Technol., 292, 122030. doi.org/10.1016/j.biortech.2019.122030.
Ioelovich, M. (2022). Features of water vapor sorption by cellulose materials. World Journ. Advanc. Res. Rev., 13(03), 254–263. https://doi.org/10.30574/wjarr.2022.13.3.0233.
Downloads
Published
Issue
Section
License
Copyright (c) 2025 Oles Honchar Dnipro National University

This work is licensed under a Creative Commons Attribution 4.0 International License.
- Authors reserve the right of attribution for the submitted manuscript, while transferring to the Journal the right to publish the article under the Creative Commons Attribution License. This license allows free distribution of the published work under the condition of proper attribution of the original authors and the initial publication source (i.e. the Journal)
- Authors have the right to enter into separate agreements for additional non-exclusive distribution of the work in the form it was published in the Journal (such as publishing the article on the institutional website or as a part of a monograph), provided the original publication in this Journal is properly referenced
- The Journal allows and encourages online publication of the manuscripts (such as on personal web pages), even when such a manuscript is still under editorial consideration, since it allows for a productive scientific discussion and better citation dynamics (see The Effect of Open Access).