CATALYTIC OXIDATION OF DICHLOROMETHANE AND TETRACHLORETHYLENE OVER NOBLE METAL CATALYSTS

Authors

  • Irada G. Malikova Institute of Catalysis and Inorganic Chemistry named after academician Murtuza Naghiyev, Azerbaijan https://orcid.org/0000-0002-7906-1556
  • Arif J. Efendi Institute of Catalysis and Inorganic Chemistry named after academician M. Nagiyevof , Azerbaijan
  • Elmir M. Babayev Institute of Catalysis and Inorganic Chemistry named after academician M. Nagiyevof , Azerbaijan
  • Aytadj M. Salakhli Institute of Catalysis and Inorganic Chemistry named after academician M. Nagiyevof , Azerbaijan
  • Konul Sh. Musazadeh Institute of Catalysis and Inorganic Chemistry named after academician M. Nagiyevof , Azerbaijan
  • Asmet N. Azizova Institute of Catalysis and Inorganic Chemistry named after academician M. Nagiyevof , Azerbaijan
  • Guseyn M. Faradjev Institute of Catalysis and Inorganic Chemistry named after academician M. Nagiyevof , Azerbaijan

DOI:

https://doi.org/10.15421/082110

Keywords:

catalytic oxidation, chlorinated volatile organic compound, dichloromethane, Tetrachloroethylene

Abstract

Among the chemicals emitted to the atmosphere, volatile organic compounds (VOCs) are classified worldwide as hazardous air pollutants. Most of the VOCs are organochlorine compounds, widely used in industryas the components of detergents and degreasers, chemical extractants, additives for paints, inks and adhesives, raw materials for drug synthesis, pesticides and polymers, solvents for chemicalsand paint strippers. These compounds are released into the atmosphere and pose a significant health hazard due to their pronounced toxicity, high stability and persistence in the environment. In this study, a total of 6 different metal monoliths containing γ-Al2O3 were studied in the oxidation of dichloromethane (DCM) and tetrachlorethylene (perchlorethylene-PCE). Pt, Pd, separately, were used as the active substances. Before the research experiments of the catalysts have been started, the water supply was optimized. Among the studied catalysts, Pt/Al2O3 was the most active in the oxidation of DCM.

Author Biography

Irada G. Malikova, Institute of Catalysis and Inorganic Chemistry named after academician Murtuza Naghiyev

Associate Professor, Candidate of Technical Sciences

References

Sudhakara, M., Vijay Kumara, V., Naresha, G., Lakshmi Kantama, M., Bhargavab, S.K., Venugopala, A. (2016). Vapor phase hydrogenation of aqueous levulinic acid over hydroxyapatite supported metal (M = Pd, Pt, Ru, Cu, Ni) catalysts. Applied Catalysis B: Environmental. 180, 113–120.

Yun, Luo, Aurelien, Habrioux, Laura, Calvillo, Gaetano, Granozzi, and Nicolas, Alonso-Vante. (2015). Thermally Induced Strains on the Catalytic Activity and Stability of Pt-M2O3/C (M=Y or Gd) Catalysts towards Oxygen Reduction Reaction. Chem. Cat. Chem, 7, 1573–1582, https://doi.org/ 10.1002/cctc.201500130

Yasuhara, A., Morita, M. (1990). Formation of Chlorinated Compounds in Pyrolysis of Trichloroethylene. Chemosphere. 21, 479–486.

Roberto, Fiorenza. (2020). Bimetallic Catalysts for Volatile Organic Compound Oxidation. Catalysts. 10, 661. https://doi.org/10.3390/catal10060661

González-Velasco, J.R, Aranzabal, A., Gutiérrez Ortiz, J.I., López-Fonseca, R., Gutiérrez-Ortiz, M.A. (1998). Activity and Product Distribution of Alumina Supported Platinum and Palladium Catalysts in the Gas-phase Oxidative Decomposition of Chlorinated Hydrocarbons. Appl Catal, B: Environ. 19, 189–197.

Pitkäaho, S., Ojala, S., Maunula, T., Savimäki, A., Kinnunen, T.&Keiski, R.L. (2011). Oxidation of dichloromethane and perchloroethylene as single compounds and inmixtures. Applied Catalysis B: Environmental, 102, 395–403.

https://doi.org/10.1016/j.apcatb.2010.12.011

He, C., Cheng, J., Zhang, X., Douthwaite, M., Pattisson, S., Hao, Z. (2019). Recent advances in the catalytic oxidation of volatile organic compounds: A review based on pollutant sorts and sources. Chem. Rev. 119(7), 4471–4568.

https://doi.org/10.1021/acs.chemrev.8b00408

Omneya El-Sharnouby, Hardiljeet K. Boparai, Jose Herrera, Denis M. O'Carroll. (2018). Aqueous-phase catalytic hydrodechlorination of 1,2-dichloroethane over palladium nanoparticles (nPd) with residual borohydride from nPd synthesis. Chemical Engineering Journal. 342, 281–292.

https://doi.org/ 10.1016/j.cej.2018.02.006

Yu, X. Ghasemizadeh, R. Padilla, I. Irizarry, C. Kaeli, D. Alshawabkeh, A. (2015). Spatiotemporal changes of CVOC concentrations in karst aquifers: Analysis of three decades of data from Puerto Rico. Science of the Total Environment. 511, 1–10.

Giraudon, J., Elhachimi, A., Leclercq, G. (2008). Catalytic Oxidation of Chlorobenzene over Pd/Perovskites. Appl. Catal B: Environ. 84(1), 251–261.

https://doi.org/10.1016/j.apcatb.2008.04.023

Pitkäaho, S., Nevanperä, T., Matejova, L., Ojala, S. & Keiski, R.L. (2013). Oxidation ofdichloromethane over Pt, Pd, Rh, and V2O5 catalysts supported on Al2O3, Al2O3–TiO2 and Al2O3–CeO2. Applied Catalysis B: Environmental. 138–139, 33–42. https://doi.org/10.1016/j.apcatb.2013.01.058

López-Fonseca, R., Gibrián, S., Gutiérrez-Ortiz, J.I., Gutiérrez-Ortiz, M.A. & Gonzáles-Velasco, J.R. (2004). Oxidative destruction of dichloromethane over protonic zeolites. A. I. Ch. E. J., 49, 496–504. https://doi.org/10.1002/aic.690490219

Wang, L., Sakurai, M. & Kameyama, H. (2008). Catalytic oxidation of dichloromethane andtoluene over platinum alumite catalyst. J. Hazard. Mater. 154, 390–395. https://doi.org/10.1016/j.jhazmat.2007.10.036

Jorengeth Abad, Rodríguez-Rodríguez, Seiling, Vargas-Villalobos, Carmen, Aparicio-Mora, Nidya, Nova-Bustos. (2020). Physical, chemical, and biological treatment of chemical waste from teaching laboratories at Universidad Nacional, Costa Rica. UNICIENCIA. 34(2), 82–94. http://dx.doi.org/10.15359/ru.34-2.5

Maria, Carmen S. Tan, Glenn G. Oyong, Chien-Chang, Shen, Consolacion, Y. Ragasa. (2018). Cytotoxic activities of the dichloromethane extracts from Andrographis paniculata (Burm. f.) nees. Journal of Natural Science, Biology and Medicine, 9(2), 201–206. https://doi.org/10.4103/jnsbm.JNSBM_91_17

Matthieu, Carton, Christine, Barul, Gwenn, Menvielle, Diane, Cyr et al. (2017). Occupational exposure to solvents and risk of head and neck cancer in women: a population-based case–control study in France. BMJ Open. 7, e012833. https://doi.org/10.1136/bmjopen-2016-012833

Marco, Zeppillia, Bruna, Matturrob, Edoardo, Dell’, Armia, Lorenzo et al. (2021). Cristiania. Reductive/oxidative sequential bioelectrochemical process for. Journal of Environmental Chemical Engineering. 9(1), 104657.

Bulka, C., Nastoupil, L.J., Koff, J.L. et al. (2016). Relations Between Residential Proximity to EPA-Designated Toxic Release Sites and Diffuse Large B-Cell Lymphoma Incidence. Southern Medical Journal, 109(10), 606–614.

https://doi.org/10.14423/SMJ.0000000000000545

Kishor, Hadkhale, Jan, Ivar Martinsen, Elisabete, Weiderpass, Kristina, Kjaerheim. (2017). Occupational exposure to solvents and bladder cancer: A population‐based case control study in Nordic countries. International Journal of Cancer, 140(8), 1736–1746. https://doi.org/10.1002/ijc.30593

Brink, R.W. van den, Mulder, P., Louw, R., Sinquin, G., Petit, & C. Hindermann J.-P. (1998). Catalytic oxidation of dichloromethane on γ-Al2O3: A combined flow and infraredspectroscopy study. J. Catal.180, 153–160.

Kiani, S., Hodabakhshi, S., Rashidi, A., Dasthoon, S. (2018). Novel One-Pot Synthesis of Pyrazolopyranopyrimidinones Using Newly Produced γ-Alumina Nanoparticles as Powerful Catalyst. Iran. J. Chem. Chem. Eng., 37(3), 63–71.

Kiani, S., Mansouri, Zadeh M., Khodabakhshi, S., Rashidi, A., Moghadasi, J. (2016). Newly Prepared Nano Gamma Alumina and Its Application in Enhanced oil Recovery: an Approach to Low-Salinity Waterflooding. Energy & Fuels, 30(5), 3791–3797.

Gianina, Dobrescu, Florica, Papa, Irina, Atkinson, Daniela, Culita, Ioan, Balint. (2021). Correlations between the basicity and the fractal dimension of Rh-nanoparticles supported on Al2O3, TiO2 and WO3. IOSR Journal of Applied Chemistry (IOSR-JAC)., 14(1), 11–25. https://doi.org/10.9790/5736-1401011125

Raphael, A.M.P. de Oliveira, Andre, L. da Silva, Lorena B. Caliman, Douglas Gouvêa. (2020). Interface excess on Li2O-doped γ-Al2O3 nanoparticles. Ceramics International, 46, 10555–1056. https://doi.org/10.1016/j.ceramint.2020.01.057

Tuomas, K. Nevanperä, Satu, Pitkäaho, Satu, Ojala and Riitta, L. Keiski. (2020). Oxidation of Dichloromethane over Au, Pt, and Pt-Au Containing Catalysts Supported on -Al2O3 and CeO2-Al2O3. Molecules. 25, 4644. https://doi.org/10.3390/molecules25204644.

Downloads

Published

2021-04-26

Issue

Vol. 29 No. 1 (2021): Journal of Chemistry and Technologies

Section

Chemical Technology

License

Copyright (c) 2021 Днипровский национальный университет имени Олеся Гончара

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

  1. Authors reserve the right of attribution for the submitted manuscript, while transferring to the Journal the right to publish the article under the Creative Commons Attribution License. This license allows free distribution of the published work under the condition of proper attribution of the original authors and the initial publication source (i.e. the Journal)
  2. Authors have the right to enter into separate agreements for additional non-exclusive distribution of the work in the form it was published in the Journal (such as publishing the article on the institutional website or as a part of a monograph), provided the original publication in this Journal is properly referenced
  3. The Journal allows and encourages online publication of the manuscripts (such as on personal web pages), even when such a manuscript is still under editorial consideration, since it allows for a productive scientific discussion and better citation dynamics (see The Effect of Open Access).